Kari Kinnunen: A phosphorus retention model

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VESIENTUTKIMUSLAITOKSEN JULKAISUJA PUBLICATIONS OF THE WATER RESEARCH INSTITUTE Guy Hällfors: A preliminary check-list of the phytoplankton of the northern Baltic Sea Tiivistelmä: Alustava pohjoisen Itämeren kasviplanktonluettelo Guy Hällfors, Terttu Melvasalo, Ake Niemi fixatives and preservatives on phytoplankton counts Hilkka Viljamaa: Effect of different Tiivistelmä: Erilaisten säilöntäaineiden vaikutus kasviplanktonin laskentatuloksiin 25 Lea Kauppi: Phosphorus and nitrogen input from rural population, agriculture and forest fertilization to watercourses Tiivistelmä: Haja-asutuksesta. maanviljelystä ja metsänlannoituksesta aiheutuva fostori- ja typpikuorma 35 3 llppo Kettunen: Horizontal differences in water quality in an area of Lake Saimaa polluted by waste waters Tiivistelmä: Veden laadun horisontaaliset erot jätevesien pilaamalla vesialueella Saimaalla 47 Tellervo Kylä-Harakka: Application of the Streeter-Phelps model to the Äänekoski watercourse, Central Finland Tiivistelmä: Streeter-Phelps-mallin soveltaminen Äänekosken vesireitille 52 KalleMatti Lappalainen, Jorma Niemi and its application to Lake Päijänne Kari Kinnunen: A phosphorus retention model Tiivistelmä: Fosforimalli ja sen soveltaminen Päijänteeseen 60 Maarit Niemi Jorma Niemi: Diurnal variation of bacteria and bacteriophages in sewage effluent and the flow time of sewage through a treatment plant Tiivistelmä: Bakteerien ja bakteriofaagien esiintyminen puhdistetussa jätevedessä vuorokauden aikana ja puhdistamon viipymän määrittäminen 68 Titta Ojanen: Phosphorus and nitrogen balance of the eutrophic Lake Tuusulanjärvi Tiivistelmä: Tuusulanjärven typpi- ja fosforitase 74 Ilkka Rinne, Terttu Melvasalo, Ake Niemi Lauri Niemistö: Nitrogenfixation (acetylene reduction method) by blue-green algae in the Baltic Sea in 1975 and 1977 Tiivistelmä: Sinilevien typensidonta Itämeressä 1975 ja 1977 88 Matti Verta, Veijo Miettinen Kirsti Erkomaa: Concentrations of chlorinated hydro carbons in pike from the Turku archipelago in the years 1970 1978 Tiivistelmä: Kloorattujen hiilivetyjen pitoisuuksista Turun saariston hauissa vuosina 1970 108 1978 VESIHALLITUS NATIONAL BOARD OF WATERS, FINLAND Helsinki 1979

ISBN 951-46-4609-6 SSN 0355-0982 Helsinki 1980. Valtion psinatuskeskus

47 HORIZONTAL DIFFERENCES IN WATER QUALJTY IN AN AREA OF LAKE SAIMAA POLLUTED BY WASTE WATERS lippo Kettunen KETTUNEN, 1. 1979. Horizontal differences in water quality in an area of Lake Saimaa polluted by waste waters. Publications of the Water Research Institute, National Board of Waters, Finland, No. 34. An investigation carried out in a part of Lake Saimaa affected by waste waters from cellulose factory indicated that the quality of littoral water differed considerably from that of the main body of water. The mostmarked differences were in oxygen concentrations, which varied from 5.4 mg 1 1 in littoral water to 1.9 mgl in the open lake. When planning investigations of polluted waters the possibile occurrance of such horizontal differences should be taken into consideration. Index words: Water quality, horizontal differences, pollution. 1. INTRODUCTION The true residence time of water in chains of lakes is often considerably less than that cal culated on the basis of lake volume (Kettunen 1971). The effects of waste waters therefore extend further down the watercourse than dilution calculations indicate. Waste materiais carried by the stream may for the same reason be more raw, with correspondingly greater effect on water quality, in ehain lakes with a strong current than in solitary lakes situated apart from the mainstream of water movement. 2. METHODS In an investigation carried out in June 1973 water quality was examined from three sam pling lines, in the southern region of Lake Sai maa, along the route followed by waste waters emitted by the factory of Kaukas Oy (Fig. 1). In addition one sampling line was chosen in a non-polluted area of Greater Saimaa. Water quality from each point of sampling was examined by means of a vertical series of water sampies. The sampies were analysed in the laboratory of National Board of Waters Kymi district office

using methods conforming to SFS standards. The results are presented as profile figures. The water region being investigated was polluted by waste waters from forest industries. Oxygen concentra tions in the water occasionally feil to below the tolerance threshold of fish populations, with consequent death of the fishes. 3. RESULTS Fig. 1. The southern region of Lake Saimaa. The sampling line A (Murheistenranta) was situated in a polluted littoral zone about 3 km from an effluent discharge point. The oxygen concentration of water very close to the shore was found to be 5.4 mg i, while 300 m from the shore concentrations were only 1.9 and 2.2 mg 1 1 in surface layers and deeper water, respectively (Fig. 2). Results from the sampling line B (Riutansal mi) showed that the most strongly polluted water was at a depth of 3 5 m (Figs. 3 and 4). Sampling line C (Kauraniemenlahti) presents a closed, eutrophic bay. lncreased oxygen con centration and turbidity recorded in the centre of the bay were probably the resuit of aigal growth (Figs. 5 and 6). Sampling line D, in a non-polluted area of Lake Saimaa, was situated in the comparatively open bay of Leviäsaari (Figs. 7 and 8). In the more eutrophic region near to the shore COD values were considerably higher than in the open lake. 0 m 1,0 2,0 3,0 =11 5,0 300 150 30 20 10 m 5 Distonce Oxygeri mg/t < 2.0 2,0 2,5 2,5 3.0 m 3,0 6,0 > 4,0 Fig. 2. Oxygen concentration. Sampling line A.

49 0 m 2 3 1. 8 10 0xyger 2 mg/l :: 2,0 3,0 Distance 1.0 2,0 <1,0 Fig. 3. Oxygen concentration. Sampling line B. 0 m 2 1. 6 8 10 C0D Fig. 4. Chemical Oxygen 2 40 80 165 147m169 Demand >20 (COD). Sampling line B. Distance 15 20 12 15 4. DISCUSSION The research carried out shows that a water mass may be divided into areas of different quality in a rather exceptional manner. The boundaries of stratified water leveis are determined by prevailing currents. In polluted areas stratification may also be due to the difference in density between effluent and non-polluted lake water. This has the effect that the effluent does not readily become diluted in the main body of water, but develops instead its own path of flow through the lake. This is clearly noticable in narrow sounds typical of the southern region of Lake Saimaa (Heinonen, Aihonen and Kettunen 1971). The present research also showed that vertical water quality boundaries do not approach the shore rectilinearly but rather follow the rising of 4 127903175V 13

Depth Depth :** 1 A;OOOOI1/1 it z c. O 1

51 the lake bottom towards the shore. in the shallow water near the shore photosynthetic and biodegrading activity have water quality. a particular effect on keessä oli liuenneen hapen määrä lähes kolmin kertainen verrattuna päällysveden arvoihin järven syvemmillä alueilla. LOPPUTI VISTELMÅ REFERENCES Veden laadun horisontaalisia eroja on tutkittu Etelä-Saimaalla selluteollisuuden pahoin likaa maila vesistöalueella. Merkittävimmät erot on havaittu happipitoisuudessa. Litoraalivyöhyk Heinonen, P., P. den taivisesta kerrostun-iisesta vialtajssa. Vesitalous 1. 1971. veden järvessä. Vesitalous 5:11 12. Kettunen, Aihonen, Kettunen, hitaasti 342 44. Havaintoja 1. 1971. virtaavjssa Jäteve jär virtauksista reitti