Interlaboratory Proficiency Test 08/2014

Transkriptio

1 REPORTS OF THE FINNISH ENVIRONMENT INSTITUTE 7 5 Interlaboratory Proficiency Test 8/ Metals and mercury in waters Mirja Leivuori, Riitta Koivikko, Timo SaraAho, Teemu Näykki, Katarina Björklöf, Keijo Tervonen, Sari Lanteri, Ritva Väisänen and Markku Ilmakunnas Finnish Environment Institute

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3 Metals and mercury in waters Mirja Leivuori, Riitta Koivikko, Timo SaraAho, Teemu Näykki, Katarina Björklöf, Keijo Tervonen Sari Lanteri, Ritva Väisänen and Markku Ilmakunnas

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5 PREFACE Finnish Environment Institute (SYKE) is appointed National Reference Laboratory in the environmental sector in Finland. The duties of the reference laboratory include providing interlaboratory proficiency tests and other comparisons for analytical laboratories and other producers of environmental information. The testing and the calibration laboratories as well as the proficiency testing provider (Proftest SYKE) of the SYKE laboratory center have been accredited by the Finnish Accreditation Services (EN ISO/IEC 75, EN ISO/IEC 7, This proficiency test has been carried out under the scope of the SYKE reference laboratory and it provides an external quality evaluation between laboratory results, and mutual comparability of analytical reliability. The success of the proficiency test requires confidential cooperation between the provider and participants. Thank you for your participation! ALKUSANAT Suomen ympäristökeskus (SYKE) toimii ympäristönsuojelulain nojalla määrättynä ympäristöalan vertailulaboratoriona Suomessa. Yksi tärkeimmistä vertailulaboratorion tarjoamista palveluista on pätevyyskokeiden ja muiden vertailumittausten järjestäminen. SYKEn laboratoriotoiminnan testaus, kalibrointi ja tutkimustoiminta sekä vertailumittausten järjestäminen (Proftest SYKE) ovat FINAS akkreditoituja (SFSEN ISO/IEC 75, SFSEN ISO/IEC 7, Tämä pätevyyskoe on toteutettu SYKEn vertailulaboratorion toimintaalueella ja se antaa ulkopuolisen laadunarvion laboratoriotulosten keskinäisestä vertailtavuudesta sekä laboratorioiden määritysten luotettavuudesta. Pätevyyskokeen onnistumisen edellytys on järjestäjän ja osallistujien välinen luottamuksellinen yhteistyö. Lämmin kiitos yhteistyöstä kaikille osallistujille! Helsinki 5 March 5 / Helsingissä 5. maaliskuuta 5 Director of Laboratory / Laboratorionjohtaja

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7 CONTENTS Introduction... 6 Organizing the proficiency test Responsibilities s Samples and delivery Homogeneity and stability studies Feedback from the proficiency test Processing the data Pretesting the data Assigned values Standard deviation for proficiency assesment and... 9 Results and conclusions.... Results.... Analytical methods Uncertainties of the results... 7 Evaluation of the results Summary... 6 Summary in Finnish... References... APPENDIX : s in the proficiency test... APPENDIX : Preparation of the samples... APPENDIX : Homogeneity of the samples... 5 APPENDIX : Feedback from the proficiency test... 6 APPENDIX 5 : Evaluation of the assigned values and their uncertainties... 7 APPENDIX 6 : Terms in the results tables... APPENDIX 7 : Results of each participant... APPENDIX 8 : Summary of the s APPENDIX 9 : s in ascending order... 8 APPENDIX : Results grouped according to the methods... 5 APPENDIX : Significant differences in the results reported using different methods... 9 APPENDIX : Estimation of the measurement uncertainties and examples of the reported values... 5 DOCUMENTATION PAGE KUVAILULEHTI PRESENTATIONSBLAD Proftest SYKE MET 8/ 5

8 Introduction Proftest SYKE carried out the proficiency test (PT) for analysis of elements in waters in October (MET 8/). The measurements were: Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V, and Zn. Four sample types were: artificial, natural water, municipal waste water and industrial waste water samples. In total 8 laboratories participated in the PT. In the PT the results of Finnish participants providing environmental data for Finnish environmental authorities were evaluated. Additionally, other water and environmental laboratories were welcomed in the proficiency test. The proficiency test was carried out in accordance with the international guidelines ISO/IEC 7 [], ISO 58 [] and IUPAC Technical report []. The Proftest SYKE has been accredited by the Finnish Accreditation Service as a proficiency testing provider (PT, ISO/IEC 7, The organizing of this proficiency test is included in the accreditation scope. Organizing the proficiency test. Responsibilities Proftest SYKE, Finnish Environment Institute (SYKE), Laboratory Centre, Hakuninmaantie 6, Helsinki, Finland Phone: , Fax The responsibilities in organizing the proficiency test were as follows: Mirja Leivuori coordinator Katarina Björklöf substitute of coordinator Riitta Koivikko proficiency test trainee Keijo Tervonen technical assistance Markku Ilmakunnas technical assistance Sari Lanteri technical assistance Ritva Väisänen technical assistance Timo SaraAho analytical expert (metals, IDICPMS) Teemu Näykki analytical expert (Hg, IDICPMS). s In total 8 participants took part in this proficiency test (Appendix ), from Finland and from other EU countries, from Kyrgyzstan and from Zambia. Altogether 7 % of the participants used accredited analytical methods at least for a part of the measurements. About 69 % of the Finnish participants provide data for use of the Finnish environmental authorities. For this proficiency test, the organizing laboratory (T, has the codes 6 (SYKE, Helsinki) and 9 (SYKE, Helsinki, IDICPMS) in the result tables. 6 Proftest SYKE MET 8/

9 . Samples and delivery Four types of samples were delivered to the participants; synthetic, natural water, municipal waste water and industrial waste water samples. The synthetic samples AM and AM were prepared from the NIST traceable commercial reference material produced by Inorganic Ventures. The synthetic sample AM was prepared by diluting Merck CertiPUR standard. The synthetic sample AHg was prepared by diluting from the NIST traceable AccuTrace TM Reference Standard produced by AccuStandard, Inc. The sample preparation is described in details in the Appendix. The synthetic samples were acidified with nitric acid with the exception of mercury sample AHg, which was acidified with the hydrochloric acid. The natural water samples NM and NHg were collected from the Lake Kattila, the southern Finland. Some additions of single element standard solutions (Merck CertiPUR ) were used in preparation of the test samples (Appendix ). The sample VM was municipal waste water with additions of single element standard solutions (Merck CertiPUR, Appendix ). The fourth samples were industrial waste water, T5Hg for Hg measurements and TN5/TY5 for measurements of other metals. These samples were prepared with additions of single element standard solutions (Merck CertiPUR, Appendix ). When preparing the samples, the purity of the used sample vessels was controlled. The randomly chosen sample vessels were filled with deionized water and the purity of the sample vessels was controlled after days by analyzing Cd, Cu, Zn and Hg. According to the test results all used vessels fulfilled the purity requirements. The samples were delivered on October to the international participants and October to the national participants. The samples arrived to the participants mainly on 5 October. s and received the samples latest on 7 October and participant 7 received the samples October. The samples were requested to be measured as follows: Mercury from the water samples latest on October (AHg, NHg and T5Hg) The other samples latest on 7 November The results were requested to be reported latest on 8 October. Basically all participants delivered the results on the requested day. The preliminary results were delivered to the participants via on 8 November.. Homogeneity and stability studies The homogeneity of the samples was tested by analyzing Cd, Cu, Mn, Zn and Hg. More detailed information of homogeneity studies is shown in Appendix. According to the homogeneity test results, all samples were considered homogenous. The synthetic samples were known to be stable and homogenous. However, homogeneity of these samples was checked by parallel measurements of three samples and they were considered to be stable. The Proftest SYKE MET 8/ 7

10 water samples have been known to be stable within the time period of the test based on the earlier similar proficiency tests..5 Feedback from the proficiency test The feedback from the proficiency test is shown in Appendix. The comments from the participants dealt mainly with sample condition after the transport and their reporting errors with the measured results of the samples. The comments from the provider are mainly focused to the lacking conversancy to the given information with the samples and the incoherent detection limits of measurement. All the feedback from the participant is valuable and is exploited when improving the activities..6 Processing the data.6. Pretesting the data The normality of the data was tested by the KolmogorovSmirnov test. The outliers were rejected according to the Grubbs or Hampel test before calculating the mean. The results which differed more than 5 % or 5 times from the robust mean were rejected before the statistical robust results handling. The replicate results were tested using the Cochrantest. If the result has been reported as below detection limit, it has not been included in the statistical calculations. More information about the statistical handling of the data is available from the Guide for participant []..6. Assigned values For the synthetic samples AM and AM the NIST traceable calculated concentrations were used as the assigned value, with the exception of Pb and Hg where the used assigned values were based on results from the metrologically traceable isotope dilution (ID) ICPMS technique. Also for the other samples for Hg and Pb (NHg, T5Hg, NM, TN5, VM, respectively) the assigned values based on the results from IDICPMS measurements were used. The IDICPMS method is accredited for soluble lead in synthetic and natural waters and for soluble mercury in synthetic, natural and waste water in the scope of calibration laboratory (K5; For the other samples and measurements the robust mean or mean value was used as the assigned value. If the number of results were low (n<), basically the mean value was reported as the assigned value (Appendix 5). The latter values are not metrologically traceable concentrations. For the calculated assigned values the expanded measurement uncertainty (k=) was estimated using standard uncertainties associated with individual operations involved in the preparation of the sample. The main individual source of the uncertainty was the uncertainty of the concentration in the stock solution. 8 Proftest SYKE MET 8/

11 In the cases when the robust means or means of the reported results were used as the assigned value, the uncertainty of the assigned value was calculated using the robust standard deviation or standard deviation of the reported results [, ]. For the metrologically traceable mercury and lead results, the uncertainty is the expanded measurement uncertainty of the IDICPMS method. The uncertainty of the calculated assigned value and the metrologically traceable value for metals in the artificial samples varied between.5 and 6 %. When using the robust mean or mean of the participant results as the assigned value, the uncertainties of the assigned values were between. % and % (Appendix 5). After reporting of the preliminary results no changes to the assigned values have been done..6. Standard deviation for proficiency assesment and The target value for the standard deviation for proficiency assessment was estimated on the basis of the analyte concentration, the results of homogeneity and stability tests, the uncertainty of the assigned value, and the longterm variation in the former proficiency tests. If the number of reported results were low, the results were not estimated (TY5: B, Sb, Se). The standard deviation for proficiency assessment at the 95% confidence level ( s p ) was set from % to 5 % depending on the measurements. After reporting the preliminary results no changes have been done for the standard deviations of the proficiency assessment values. When using the robust mean or mean as the assigned value, the reliability was tested according to the criterion u / s p., where u is the standard uncertainty of the assigned value (the expanded uncertainty of the assigned value (U) divided by ) and s p is the standard deviation for proficiency assessment []. When testing the reliability of the assigned value the criterion was mainly fulfilled and the assigned values were considered reliable. The reliability of the target value of the standard deviation and the corresponding was estimated by comparing the deviation for proficiency assessment (s p ) with the robust standard deviation of the reported results (s rob ) []. The criterion s rob / s p <. was mainly fulfilled. In the following cases, the criterion for the reliability of the assigned value and/or for the reliability of the target value for the deviation was not met and, therefore, the evaluation of the performance is weakened in this proficiency test: Sample Measurement NM Pb, Sn, TN5 B, Co,, Fe, Mn, Ni, Se, TY5 Al,, Pb VM Al, Proftest SYKE MET 8/ 9

12 Results and conclusions. Results The terms used in the result sheet are show in Table 6. The results and the performance of each laboratory are presented in Appendix 7 and the summary of the results in Table. The results of the replicate determinations are presented in Table (ANOVA statistics).the summary of the s is shown in Appendix 8 and s in the ascending order in Appendix 9. The reported results grouped by the used analytical methods with their expanded uncertainties (k=) are presented in Appendix. The robust standard deviations of the results varied from. % to. % (Table ). The robust standard deviation of results was lower than % for 8 % of the results and lower than % for 99 % of the results (Table ). Standard deviations higher than % apply only to the industrial waste water sample (TY5: B). The robust standard deviations were approximately in the same range as in the previous similar proficiency test Proftest SYKE proficiency test for artificial and water samples [5], where the deviations varied from.6 % to.8 %. The robust standard deviation was not calculated when the number of results within the statistical evaluation was low (< 7, TY5: Sb, Se). Table. The summary of the results in the proficiency test 8/. Analyte Sample Unit Assigned value Mean Rob. mean Median SD rob SD rob % *sp % n (all) Acc z % Al AM AM NM TN TY VM As AM AM NM TN TY VM B AM mg/l AM mg/l NM mg/l TN5 mg/l TY5 mg/l VM mg/l Cd AM AM NM TN TY VM Proftest SYKE MET 8/

13 Table. The summary of the results in the proficiency test 8/. Analyte Sample Unit Assigned value Mean Rob. mean Median SD rob SD rob % *sp % n (all) Acc z % Co AM AM NM TN TY VM Cr AM AM NM TN TY VM Cu AM AM NM TN TY VM Fe AM AM NM TN TY VM Hg AHg NHg T5Hg Mn AM AM NM TN TY VM VM Mo AM AM NM TN TY VM Ni AM AM NM TN TY VM Proftest SYKE MET 8/

14 Table. The summary of the results in the proficiency test 8/. Analyte Sample Unit Assigned value Mean Rob. mean Median SD rob SD rob % *sp % n (all) Acc z % Pb AM AM NM TN TY VM Sb AM AM NM TN5.6 TY VM Se AM AM NM TN TY VM Sn AM NM V AM AM NM TN TY VM Zn AM AM NM TN TY VM Rob. mean: the robust mean, SD rob: the robust standard deviation, SD rob %: the robust standard deviation as percent, *s p %: the standard deviation for proficiency assessment at the 95 % confidence interval, Acc z %: the results (%), where ïzï, n(all): the total amount of the participants. In this PT the participants were requested to report duplicate results for all measurements. The participants reported the replicates with the exception of some laboratories (e.g. s,,, 7 for some elements). The results of the replicate determinations based on the ANOVA statistical handling are presented in Table. The estimation of the robustness of the methods could be done by the ratio s b /s w. The ratio s b /s w should not exceed value for robust methods. However, here in many cases the robustness exceeded the value ; the ratio varied between.6 and (Table ). Proftest SYKE MET 8/

15 Table. The summary of repeatability on the basis of duplicate determinations (ANOVA) statistics. Analyte Sample Unit Ass.val. Mean sw sb st sw% sb% st% sb/sw Al AM AM NM TN TY VM As AM AM NM TN TY VM B AM mg/l AM mg/l NM mg/l TN5 mg/l TY5 mg/l VM mg/l Cd AM AM NM TN TY VM Co AM AM NM TN TY VM Cr AM AM NM TN TY VM Cu AM AM NM TN TY VM Proftest SYKE MET 8/

16 Table. The summary of repeatability on the basis of duplicate determinations (ANOVA) statistics. Analyte Sample Unit Ass.val. Mean sw sb st sw% sb% st% sb/sw Fe AM AM NM TN TY VM Hg AHg NHg T5Hg Mn AM AM NM TN TY VM VM Mo AM AM NM TN TY VM Ni AM AM NM TN TY VM Pb AM AM NM TN TY VM Sb AM AM NM TN TY VM Se AM AM NM TN TY VM Proftest SYKE MET 8/

17 Table. The summary of repeatability on the basis of duplicate determinations (ANOVA) statistics. Analyte Sample Unit Ass.val. Mean sw sb st sw% sb% st% sb/sw Sn AM NM V AM AM NM TN TY VM Zn AM AM NM TN TY VM Ass.val.: assigned value; s w : repeatability standard error; s b : standard error between laboratories; s t : reproducibility standard error.. Analytical methods The participants were allowed to use different analytical methods for the measurements in the PT. The used analytical methods and results of the participants grouped by methods are shown in more detail in Appendix. The statistical comparison of the analytical methods was possible for the data where the number of the results was 5. Effect of sample pretreatment on elemental concentrations in waste waters Elements in waste water were mainly measured from acidified samples without sample pretreatment with the exception of the industrial waste water sample (TN5/TY5). In average, 59 % of the participants measured the acidified industrial waste water without sample pretreatment (TN5), and the other participants measured the industrial waste water after nitric acid digestion (TY5). These results were evaluated separately. The difference between the average concentrations of elements measured by different sample preparation methods was tested using the ttest. No statistical differences were observed between without pretreatment method (TN5) and nitric acid digested results (TY5). The graphical result evaluation showed that in 69 % of cases, no pretreatment method (TN5) gave slightly lower result that the method with nitric acid digestion (TY5). Effect of measurement methods on elemental results The most commonly used analytical method was ICPMS, followed by ICPOES. Some participants used GAAS and only few participants used FAAS technique or other techniques (Appendix ). The statistical comparison (ttest) for the average concentrations of metals measured with different measurement methods was done for the data where the number of Proftest SYKE MET 8/ 5

18 reported results was 5. There were some statistically significant differences between the results obtained using different methods from some analyses of one sample (Appendix ): Measurement methods ICPOES / ICPMS Metal/Sample Fe /TN5; Mo/TN5; Pb/TN5 In all cases where the difference was statistically significant, ICPOES results were lower than ICPMS results. As a general note, a low recovery may be an indication of loss of analyte which can occur during sample pretreatment (e.g. volatilization during acid digestion) or measurement (e.g. GAAS analysis). It may also be caused by incorrect background correction (ICPOES) or matrix effects. Recoveries that are too high may be caused by spectral interferences (overlapping wavelengths in emission spectrometry, polyatomic or isobaric interferences in mass spectrometry), matrix effects or contamination. Matrix effects can often be overcome by matrix matching the calibration standards, however this is often difficult with environmental samples since the elemental concentrations vary a lot even within the same sample type. Effect of measurement methods on mercury results The used oxidants in mercury analyses for water samples were reported to be: KMnO /K S O 8, KBr/KBrO, KMnO, and SnCl solutions. Mercury was measured mostly using cold vapor CVAFS or ICPMS instruments. Also CVAAS and CVICPMS instruments were used. No statistically significance differences between the used measuring methods were found. As for other metal determinations, also mercury results are affected by digestion procedures used (acids and oxidation reagents used, their concentration, amounts and purities, digestion temperature and time). For water samples hydrochloric acid is recommended to be used for sample preservation and BrCl is recommended to be used for oxidation of mercury species. Generally, the differences in mercury results are mainly due to different pretreatment procedures. Due to the matrix of the industrial waste water (TNHg), longer oxidation time might be required than for natural water samples. On the stability studies oxidation time of overnight resulted higher concentrations than for shorter oxidation time. Analytical techniques do not have so much effect on the results, but the fact is that, for example, using CVAFS lower detection limits can be achieved compared to CVAAS. CVICPMS technique is known to have very competent detection limits as well. 6 Proftest SYKE MET 8/

19 . Uncertainties of the results Totally 77 % of the participants reported the expanded uncertainties (k=) with their results for at least some of their results (Table, Appendix ). The range of the reported uncertainties varied between the measurements and the sample types. As can be seen in Table, many of the participants have clearly under or overestimated their expanded (k=) measurement uncertainty. Expanded measurement uncertainty below 5% is not common for routine laboratories. Also measurement uncertainty over 5% should not exist, unless the measured concentration is near to the limit of quantification. Laboratories are advised to report their (relative) measurement uncertainty as a whole number (e.g. 7% or 5%). In order to promote the enhancement of environmental measurements quality standards and traceability, the national quality recommendations for data entered into water quality registers have been published in Finland [6]. The recommendations for measurement uncertainties for tested analytes in natural waters are 5 % and for some tested metals in waste waters %. In this proficiency test some of the participants had their measurement uncertainties within these limits, while some did not achieve them. Nevertheless, harmonization of the uncertainties estimation should be continued. Several approaches were used for estimating of measurement uncertainty (Appendix ). The most used approach was based on the internal quality data or data obtained in method validation (Method and Method, Appendix ). Depending on the tested elements, laboratories used MUkit measurement uncertainty software for the estimation of their uncertainties. The free software is available in the webpage: Generally, the used approach for estimating measurement uncertainty did not make definite impact on the uncertainty estimates. Table. The range of the expanded measurement uncertainties (k=, U %) reported by the participants. Analyte AM/AHg, % AM/AM, % NM/NHg, % VM, % TN5/T5Hg, % TY5, % Al As B Cd Co Cr Cu Fe Hg Mn Mo Ni Pb Sb Se Sn 55 5 V Zn Proftest SYKE MET 8/ 7

20 Evaluation of the results The evaluation of the participants was based on the s, which were calculated using the assigned and the estimated target values for the total deviation (Appendix 7). The s were interpreted as follows: Criteria Performance z Satisfactory < z < Questionable z ³ Unsatisfactory In total, 86 % of the results were satisfactory when total deviation of 5 % from the assigned values were accepted. Altogether 7 % of the participating laboratories used accredited analytical methods for at least part of the measurements and 76 % of their results were satisfactory. The summary of the performance evaluation and comparison to the previous performance is presented in Table. In the previous similar PT, Proftest SYKE / [5], the performance was satisfactory for 9 % of the all participants. Noticeable is that in the previous PT also sludge samples were measured, which were missing in the present proficiency test. Further, in the present proficiency test some participants are from the emerging laboratories participating via bilateral development cooperation projects. The analytical quality of these laboratories caused some decrease to the total amount of satisfactory results of participants. The satisfactory results varied between 8 % and 9 % for the tested sample types (Table ). The share of satisfactory results in the artificial sample AM was the lowest for B, Pb and Sb, around 7 %. The comparison to the previous proficiency test for low concentration artificial sample is not possible as in the proficiency test was not organized in the same was as usual [5]. For the high concentration artificial sample (AM) the share of satisfactory results was in the same level than in the previous test in [5]. In the natural water sample NM all results for Se and V were satisfactory. The share of satisfactory results in the sample NM was the lowest for Cu, Pb and Zn, around 7 %. The comparison to the previous proficiency test is not possible as the test was organized differently [5]. 8 Proftest SYKE MET 8/

21 Table. Summary of the performance evaluation in the proficiency test Proftest SYKE MET 8/. Sample Satisfactory Accepted deviation from Remarks results (%) the assigned value (%) AM /AHg 8/85 Difficulties in measurements for Al, B, Cd, Cu, Fe, Pb, Sb for which there were < 8% satisfactory results. In the PT / the performance was satisfactory for 9 % of mercury measurements [5]. AM 86 5 Difficulties in measurements for Al and Cr for which there were < 8% satisfactory results. In the PT / the performance was satisfactory for 86 % of the same level artificial sample [5]. AM 85 Satisfactory performance, thus in the PT/ the performance was satisfactory for 9 % of the Sn results [5]. NM, NHg 86 5 Somewhat approximate performance evaluation for Pb (high variability) and Sn (low number) results. Difficulties in measurements for Cd, Cu, Pb, Sn, Zn for which was < 8% satisfactory results. TN5/T5Hg 86/89 Somewhat approximate performance evaluation for B, Co, Fe, Mn, Ni and Se. Difficulties in measurements for Al, B, Fe, Pb for which was < 8% satisfactory results. In the PT / the performance was satisfactory also for 89 % of mercury measurements [5]. TY5 8 High uncertainty of the assigned value for: Al, Pb. Difficulties in measurements for Mo for which was < 8% satisfactory results. In the PT / the performance was satisfactory for 9 % of the results [5]. VM 9 5 Somewhat approximate performance evaluation for Al. Difficulties in measurements for Cu for which was < 8% satisfactory results. In the PT / the performance was satisfactory for 9 % of the results [5]. For Co, Ni and Zn in the sample TY5 and for Sb in the sample TN5 all results were satisfactory when accepting the deviation of 5 % from the assigned value (Table ). For the waste water samples (VM and TN5/TY5) 86 % of the results were satisfactory, when deviations of % from the assigned value were accepted. This in the same level as in the previous proficiency test of waste water samples, when 88 % of results were accepted accepting the deviations of 5 % from the assigned value [5]. Proftest SYKE MET 8/ 9

22 5 Summary Proftest SYKE carried out the proficiency test (PT) for analysis of elements in waters in October. The measurements were: Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V, and Zn. Four sample types were: artificial, natural water, municipal waste water and industrial waste water samples. In total 8 laboratories participated in the PT. For the synthetic samples AM and AM the NIST traceable calculated concentrations were used as the assigned values. For the assigned values of Hg and Pb (NHg, T5Hg, NM, TN5, VM, respectively) the results based on the metrologically traceable isotope dilution (ID) ICPMS technique results were used. For the other samples the theoretical concentration, the robust mean or the mean of the results reported by the participants was chosen to be the assigned value. The uncertainty for the assigned value was estimated at the 95 % confidence interval and it was generally between.5 and 6 % for the calculated and metrologcally traceable assigned values and for assigned values based on the robust mean or mean of the results it was between. %. The evaluation of the performance was based on the s, which were calculated using the standard deviation for proficiency assessment at 95 % confidence level. In this proficiency test 86 % of the data was regarded to be satisfactory when the result was accepted to deviate from the assigned value to 5 %. About 7 % of the participants used accredited methods and 76 % of their results were satisfactory. 6 Summary in Finnish Proftest SYKE järjesti ympäristönäytteitä analysoiville laboratorioille pätevyyskokeen lokakuussa. Pätevyyskokeessa määritettiin Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V ja Zn synteettisestä näytteestä sekä kolmesta erityyppisestä vesinäytteestä. Pätevyyskokeeseen osallistui yhteensä 8 laboratoriota. Mittaussuureen vertailuarvona käytettiin laskennallista pitoisuutta tai osallistujien tulosten robustia keskiarvoa tai keskiarvoa. Lyijylle ja elohopealle käytettiin metrologisesti jäljitettävää tavoitearvoa osassa testinäytteistä. Vertailuarvolle laskettiin mittausepävarmuus 95 % luottamusvälillä. Vertailuarvon laajennettu epävarmuus oli,5 ja 6 % välillä laskennallista tai metrologisesti jäljitettävää pitoisuutta vertailuarvona käytettäessä ja muilla välillä, %. Pätevyyden arviointi tehtiin zarvon avulla ja tulosten sallittiin poiketa vertailuarvosta 5 %. Koko aineistossa hyväksyttäviä tuloksia oli 86 %. Noin 7 % osallistujista käytti akkreditoituja määritysmenetelmiä ja näistä tuloksista oli hyväksyttäviä 76 %. Proftest SYKE MET 8/

23 REFERENCES. SFSEN ISO 7,. Conformity assessment General requirements for Proficiency Testing.. ISO 58, 5. Statistical methods for use in proficiency testing by interlaboratory comparisons.. Thompson, M., Ellison, S. L. R., Wood, R., 6. The International Harmonized Protocol for the Proficiency Testing of Analytical Chemistry laboratories (IUPAC Technical report). Pure Appl. Chem. 78: 596, Proftest SYKE Guide for laboratories: Running proficiency test ( ECE96D8C%7D/9886). 5. Leivuori, M., KorhonenYlönen, K., SaraAho, T., Näykki, T., Tervonen, K., Lanteri, S. and Ilmakunnas, M.. SYKE Proficiency Test /. Metals in waters and sludge. Reports of Finnish Environment Institute /. Helsinki. ( 6. Näykki, T., Kyröläinen, H., Witick, A., Mäkinen, I. Pehkonen, R., Väisänen, T., Sainio, P. ja Luotola M.. Laatusuositukset ympäristöhallinnon vedenlaaturekistereihin vietävälle tiedolle: Vesistä tehtävien analyyttien määritysrajat, mittausepävarmuudet sekä säilytysajat ja tavat. (Quality recommendations for data entered into the environmental administration s water quality registers: Quantification limits, measurement uncertainties, strorage times and methods associated with analytes determined from waters). Ympäristöhallinnon ohjeita /. (Environmental administration Guidelines /). 5 s. Proftest SYKE MET 8/

24 APPENDIX (/) APPENDIX : s in the proficiency test Country Denmark Finland Kyrgyz Republic Sweden Zambia Name of participant Eurofins Miljø A/S, Vejen Force Holstebro, Holstebro Ahma Ympäristö Oy, Oulu Boliden Harjavalta Oy, Harjavalta Boliden Kokkola Oy, Kokkola Danisco Sweetners Oy, Kotka Ekokem Oy Ab, Riihimäki Eurofins Scientific Finland Oy, Kokkola Eurofins Viljavuuspalvelu, Mikkeli Freeport Cobalt Oy, Kokkola Hortilab Oy Ab, Närpiö Jyväskylän ympäristölaboratorio, Jyväskylä KCL Kymen laboratorio Oy, Kuusankoski Kokemäenjoen vesistön vesiensuojeluyhdistys ry, Tampere LounaisSuomen vesi ja ympäristötutkimus Oy, Turku MetropoliLab Oy, Helsinki Metsäntutkimuslaitos, Vantaa Nab Labs Oy, Ambiotica, Jyväskylä Norilsk Nickel Harjavalta Oy, Harjavalta Novalab Oy, Karkkila Outokumpu Stainless Oy, Tornio Porilab, Pori Ramboll Analytics, Lahti Sachtleben Pigments Oy, Pori SSAB Europe Oy, Hämeenlinna SSAB Europe Oy, Raahe SavoKarjalan ympäristötutkimus Oy, Kuopio SeiLab Oy, Seinäjoki SGS Inspection Services Oy, Kotka SYKE, Laboratoriokeskus, Helsinki UPM Tutkimuskeskus, Lappeenranta UPM Tervasaari, Valkeakoski ÅMHM laboratoriet, Jomala SAEPF, IssykKulNaryn, CholponAta City SAEPF, Bishkek ITM, Stockholm University, Stockholm NEAAS, National Institute for scientific and industrial research ZABS, Zambia Bureau of Standards Proftest SYKE MET 8/

25 APPENDIX (/) APPENDIX : Preparation of the samples The artificial samples AM and AM were prepared by diluting from the NIST traceable certified reference materials produced by Inorganic Ventures. The artificial sample AM was prepared by diluting from the Merck CertiPUR standard. The artificial sample AHg was prepared by diluting from the NIST traceable AccuTrace TM Reference Standard produced by AccuStandard, Inc. The water samples NM, VM, T5M, (TN5/TY5) and T5Hg were prepared by adding some separate metal solutions (Merck CertiPUR ) into the original water sample, if the original concentration was not high enough. Al As B Cd Co Cr Cu Fe Hg Mn Analyte Original Dilution Addition Ass. value Original Dilution Addition Ass. value Original Dilution Addition Ass. value Original Dilution Addition Ass. value Original Dilution Addition Ass. value Original Dilution Addition Ass. value Original Dilution Addition Ass. value Original Dilution Addition Ass. value Original Dilution Addition Ass. value Original Dilution Addition Ass. value AM AM AM NM VM TN5/TY5 87 5/ / /86.../.. / / / / 8 9/89 AHg <..5.5 NHg < T5Hg..5.6 Proftest SYKE MET 8/

26 APPENDIX (/) Proftest SYKE MET 8/ Analyte AM AM AM NM VM TN5/TY5 AHg NHg T5Hg Mo Original Dilution Addition Ass. value /85 Ni Original Dilution Addition Ass. value /8 Pb Original Dilution Addition Ass. value /79. Sb Original Dilution Addition Ass. value / Se Original Dilution Addition Ass. value /8.9 Sn Original Dilution Addition Ass. value V Original Dilution Addition Ass. value /5 Zn Original Dilution Addition Ass. value /8 Original = the original concentration Dilution = the ratio of dilution Addition = the addition concentration Ass. value = the assigned value

27 APPENDIX (/) APPENDIX : Homogeneity of the samples Homogeneity was tested from duplicate measurements of selected measurement from eight samples of each sample types (Table ). Table. Results from the homogeneity testing of the different measurements and samples. Measurement/ sample Concentration sh % sp % sh san san/sh Is san/sh<.5? ssam ssam c Is ssam <c? Cd/NM....9 YES... YES Cu/NM YES YES Mn/NM YES YES Zn/NM YES.5..6 YES Cd/VM YES..7. YES Cu/VM YES.6..5 YES Mn/VM YES YES Zn/VM YES... YES Cd/T5M / YES...6 YES Cu/T5M YES... YES Mn/T5M 5/ YES... YES Zn/T5M YES...68 YES IDICPMS testing Hg/NHg* YES... YES Hg/T5Hg* YES... YES Pb/NM* YES... YES Pb/VM* YES.5..6 YES Pb/T5M* / YES..9. YES *) result based on the IDICPMS measurement s p % = standard deviation for proficiency assessment s h % = standard deviation for testing of homogeneity s an = analytical deviation, standard deviation of the results in a sub sample s sam = betweensample deviation, standard deviation of the results between sub samples c = F s all + F s an where: s all = (. s p ) F =. and F =.5, when the number of sub samples is 8 Conclusion: In each case, the criteria were fulfilled, and thus all the samples could be regarded as homogenous. Proftest SYKE MET 8/ 5

28 APPENDIX (/) APPENDIX : Feedback from the proficiency test Comments on technical excecution Action / Proftest, 7 Bottles of samples AHg and T5Hg had leaked. The participants did not request new samples despite of the indication of leaking. The provider will be more careful with tightening of the glass sample bottles., Bottle of sample T5Hg had leaked. The participants received the new samples. 9 The participant wished larger sample volumes. The larger volumes of samples will cause increasing cost of sample preparation, sample testing and transportation, and finally the participation fee. This action should be very carefully weighed up before any activity. The participant can order more sample bottles if the informed volume of sample did not fulfill their needs. The naming of results sheet has not worked correctly. The result sheet of the participant was corrected by the provider before data handling. This information will be noted in the forthcoming tests. Comments to the results Action / Proftest The participant informed that they reported result of Cd erroneously in the column of Co for the sample TN5. The result was an outlier in the statistical treatment, and thus it did not affect the performance evaluation. If the result had been reported correctly, it would have been satisfactory. The participant can recalculate s according to the guide for participating laboratories []. 6 The participant had measured and reported Hg samples from the previous proficiency test instead of the present test, but later measured the correct samples. The participant informed that there were no data input possibility for the sample TM5 in the result sheet. FEEDBACK TO THE PARTICIPANTS The participant can recalculate s according to the guide for participating laboratories []. The information was available in the cover letter of the samples, the sample code changed based on the pretreatment method. was newly instructed accordingly. Comments 8,,,,7 The participants reported only one result in their dataset, though replicate results were requested. These results were not included in the calculation of assigned values. The provider recommends the participants to follow the given guidelines. 9 The participant informed their detection limit as < µl/g for As in the sample NM. The assigned value was. µl/g and thus the participant should be able to measure it. The provider recommends the participant to validate their detection limit. 7 The participant informed their detection limit (DL) as < 6 µl/g and for Cr in the sample NM. The assigned value was 7.8 µl/g and thus the participant should be able to measure it. The case were similar for Cu in the samples AM, NM, VM (DL< µl/g), for Pb in the sample AM (DL< µl/g) and for Zn in the sample VM (DL< µl/g), where the assigned value were higher than the detection limit reported by the participants. The provider recommends the participant to validate their detection limits. 7 The participant informed their detection limit (DL) as < 6 µl/g and for Cr in the sample NM. The assigned value was 7.8 µl/g and thus the participant should be able to measure it. The case were similar for Cu in the samples AM, NM, VM (DL< µl/g), for Pb in the sample AM (DL< µl/g) and for Zn in the sample VM (DL< µl/g), where the assigned value were higher than the detection limit reported by the participants. The provider recommends the participant to validate their detection limits. In the database of the test there were in total 5 results which were Cochran outliers. The provider recommends the participants to validate their deviation of replicate measurements. 6 Proftest SYKE MET 8/

29 APPENDIX 5 (/) APPENDIX 5: Evaluation of the assigned values and their uncertainties Analyte Sample Unit Assigned value Expanded uncertainty Expanded Uncertainty, % Evaluation method of assigned value u/sp Al AM 5..7 Calculated value. AM Calculated value.6 NM 5.5 Robust mean. TN5 5.5 Mean.7 TY Mean.6 VM 7.9 Robust mean. As AM...8 Calculated value.5 AM 5..7 Calculated value.5 NM...8 Robust mean.5 TN Robust mean. TY Mean.5 VM Robust mean. B AM mg/l.5..9 Calculated value.5 AM mg/l 95.6 Calculated value. NM mg/l Mean.5 TN5 mg/l Mean. TY5 mg/l 86 Mean VM mg/l Robust mean.9 Cd AM...9 Calculated value. AM Calculated value.5 NM Robust mean. TN5... Robust mean.8 TY Robust mean. VM Robust mean. Co AM.5..8 Calculated value.5 AM Calculated value.7 NM... Robust mean. TN Robust mean. TY Robust mean.7 VM.5..9 Robust mean.6 Cr AM.5..7 Calculated value.5 AM Calculated value.6 NM Robust mean.7 TN Robust mean. TY Mean.5 VM.5.5. Robust mean. Cu AM.5..8 Calculated value.5 AM Calculated value.7 NM. Robust mean. TN Robust mean.9 TY Mean. VM Mean. Proftest SYKE MET 8/ 7

30 APPENDIX 5 (/) Analyte Sample Unit Assigned value Expanded uncertainty Expanded Uncertainty, % Evaluation method of assigned value u/sp Fe AM Calculated value.6 AM Calculated value.5 NM 76. Robust mean. TN Robust mean.6 TY Mean.5 VM 8.6 Robust mean. Hg AHg.5.6. IDICPMS.5 NHg IDICPMS. T5Hg.6.8. IDICPMS.5 Mn AM Calculated value.6 AM 5.8 Calculated value.8 NM.9.. Robust mean. TN Robust mean.8 TY Mean.7 VM 7 7. Robust mean. Mo AM...9 Calculated value.9 AM.7 Calculated value.7 NM Robust mean. TN5 8. Robust mean. TY Mean. VM Robust mean. Ni AM Calculated value.5 AM Calculated value.6 NM.6..7 Robust mean.5 TN Robust mean.8 TY5 8.6 Mean. VM Robust mean.5 Pb AM.6.. IDICPMS. AM IDICPMS. NM.6.. IDICPMS. TN IDICPMS. TY Robust mean.9 VM IDICPMS. Sb AM.5..8 Calculated value.8 AM 65.8 Calculated value.8 NM Mean.7 TN Mean.6 TY5. Mean.6 VM Robust mean. Se AM.5..7 Calculated value.5 AM Calculated value.5 NM Robust mean.8 TN Robust mean. TY Mean.5 VM Robust mean. Sn AM Calculated value. NM.5.9. Mean. V AM Calculated value.5 AM Calculated value.6 8 Proftest SYKE MET 8/

31 APPENDIX 5 (/) Analyte Sample Unit Assigned value Expanded uncertainty Expanded Uncertainty, % Evaluation method of assigned value u/sp NM Robust mean.6 TN Robust mean. TY5 5. Mean.6 VM..5.6 Robust mean. Zn AM Calculated value.5 AM 55.5 Calculated value.5 NM Robust mean.9 TN Robust mean. TY Robust mean. VM Robust mean. Metrologically traceable value Criterion for reliability of the assigned value u/s p <., where: s p = target value of the standard deviation for proficiency assessment u = standard uncertainty of the assigned value Proftest SYKE MET 8/ 9

32 APPENDIX 6 (/) APPENDIX 6: Terms in the results tables Results of each participant Analyte The tested parameter Sample The code of the sample Calculated as follows: z = (x i X)/s p, where x i = the result of the individual laboratory X = the reference value (the assigned value) s p = the target value of the standard deviation for proficiency assessment Assigned value The reference value s p % The target value of total standard deviation for proficiency assessment (s p ) at the 95 % confidence level Lab s result The result reported by the participant (the mean value of the replicates) Md Median Mean Mean SD Standard deviation SD% Standard deviation, % n (stat) Number of results in statistical processing Summary on the s S satisfactory ( z ) Q questionable ( < z < ), positive error, the result deviates more than s p from the assigned value q questionable ( < z < ), negative error, the result deviates more than s p from the assigned value U unsatisfactory (z ), positive error, the result deviates more than s p from the assigned value u unsatisfactory (z ), negative error, the result deviates more than s p from the assigned value Robust analysis The items of data are sorted into increasing order, x, x, x i,,x p. Initial values for x * and s * are calculated as: x * = median of x i (i =,,...,p) s * =,8 median of x i x * (i =,,...,p) The mean x * and s * are updated as follows: Calculate φ =.5 s *. A new value is then calculated for each result x i (i =, p): { x * φ, if x i < x * φ x * i = { x * + φ, if x i > x * + φ, { x i otherwise The new values of x * and s * are calculated from: * * x = å xi / p * * * s =. å( xi x ) /( p ) The robust estimates x * and s * can be derived by an iterative calculation, i.e. by updating the values of x * and s * several times, until the process convergences []. Proftest SYKE MET 8/

33 APPENDIX 7 (/5) APPENDIX 7: Results of each participant Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) As AM TN Cd AM TN Co AM TN Cu AM AM NM TN Ni AM AM TN Zn AM AM NM TN Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TY VM As AM. 5 < AM NM. 5 < TY VM 6.8 < B mg/l AM.5 < mg/l AM mg/l NM 5.8 < mg/l TY mg/l VM Cd AM. < AM NM. <..... TY VM Co AM AM NM TY VM Proftest SYKE MET 8/

34 APPENDIX 7 (/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cr AM.5 5 < AM NM < TY VM Cu AM.5 5 < AM NM TY VM 6.8 < Fe AM AM NM TY VM Hg AHg NHg.89 5 < T5Hg Mn AM AM NM TY VM Mo AM AM NM 8.96 < TY VM Ni AM < AM NM TY VM 6.6 < Pb AM.6 5 < AM NM.6 5 < TY VM < Sb AM.5 < AM NM.78 < TY VM < Se AM.5 5 < AM NM.8 < TY VM 6.6 < Proftest SYKE MET 8/

35 APPENDIX 7 (/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Sn AM NM.5 5 < V AM < AM NM.9 5 < TY VM. 5 < Zn AM AM NM TY VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN VM As AM AM NM TN VM B mg/l AM mg/l AM mg/l NM mg/l TN mg/l VM Cd AM AM NM TN VM Co AM AM NM TN VM Cr AM AM NM TN VM Proftest SYKE MET 8/

36 APPENDIX 7 (/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cu AM AM NM TN VM Fe AM AM NM TN VM Hg AHg NHg T5Hg Mn AM AM NM TN VM Mo AM AM NM TN VM Ni AM AM NM TN VM Pb AM AM NM TN VM Sb AM AM NM TN VM Se AM AM NM TN VM Sn AM NM Proftest SYKE MET 8/

37 APPENDIX 7 (5/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) V AM AM NM TN VM Zn AM AM NM TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) As AM TN Co TN Cr AM TN Fe AM AM TN Mn AM AM TN Mo AM TN Ni AM TN Pb AM TN Sb AM TN Se AM TN Zn AM TN Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN VM Proftest SYKE MET 8/ 5

38 APPENDIX 7 (6/5) 5 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) As AM AM NM TN VM B mg/l AM mg/l AM mg/l NM mg/l TN mg/l VM Cd AM AM NM TN VM Co AM AM NM TN VM Cr AM AM NM TN VM Cu AM AM NM TN VM Fe AM AM NM TN VM Hg AHg NHg.89 5 < T5Hg Mn AM AM NM TN VM Mo AM AM NM TN VM Proftest SYKE MET 8/

39 APPENDIX 7 (7/5) 5 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Ni AM AM NM TN VM Pb AM AM NM TN VM Sb AM AM NM TN VM Se AM AM NM TN VM Sn AM NM V AM AM NM TN VM Zn AM AM NM TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN VM As AM AM NM TN VM Proftest SYKE MET 8/ 7

40 APPENDIX 7 (8/5) 6 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) B mg/l AM mg/l AM mg/l NM mg/l TN mg/l VM Cd AM AM NM TN VM Co AM AM NM TN VM Cr AM AM NM TN VM Cu AM AM NM TN VM Fe AM AM NM TN VM Hg AHg NHg T5Hg Mn AM AM NM TN VM Mo AM AM NM TN VM Ni AM AM NM TN VM Proftest SYKE MET 8/

41 APPENDIX 7 (9/5) 6 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Pb AM AM NM TN VM Sb AM AM NM TN VM Se AM AM NM TN VM Sn AM NM V AM AM NM TN VM Zn AM AM NM TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM TN VM As AM AM TN VM B mg/l AM mg/l AM mg/l TN mg/l VM Cd AM AM TN VM Proftest SYKE MET 8/ 9

42 APPENDIX 7 (/5) 7 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Co AM AM TN VM Cr AM AM TN VM Cu AM AM TN VM Fe AM AM TN VM Mn AM AM TN VM Mo AM AM TN VM Ni AM AM TN VM Pb AM AM TN VM Sb AM AM TN VM Se AM AM TN VM Sn AM V AM AM TN VM Proftest SYKE MET 8/

43 APPENDIX 7 (/5) 7 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Zn AM AM TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN VM As AM AM NM TN VM B mg/l AM mg/l AM mg/l NM mg/l TN mg/l VM Cd AM AM NM TN VM Co AM AM NM TN VM Cr AM AM NM TN VM Cu AM AM NM TN VM Fe AM AM NM TN VM Proftest SYKE MET 8/

44 APPENDIX 7 (/5) 8 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Mn AM AM NM TN VM Mo AM AM NM TN VM Ni AM AM NM TN VM Pb AM AM NM TN VM Sb AM AM NM TN VM Se AM AM NM TN VM V AM AM NM TN VM Zn AM AM NM TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM TY VM Proftest SYKE MET 8/

45 APPENDIX 7 (/5) 9 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) As AM AM NM TY VM Cd AM AM NM TY VM Cr AM AM TY VM Cu NM Hg AHg T5Hg Ni AM AM NM TY VM Pb AM AM NM TY VM Zn NM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Ni TN Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM Cu AM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM Cd AM AM NM Proftest SYKE MET 8/

46 APPENDIX 7 (/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cu AM AM NM Fe AM AM NM Mn AM AM NM Mo AM AM NM Pb AM AM NM Zn AM AM NM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al TY As AM Cd TY Co AM TY Cr AM TY Cu AM TY Fe TY Hg AHg T5Hg Mn TY Mo TY Ni AM TY Pb AM TY V AM TY Zn AM TY Proftest SYKE MET 8/

47 APPENDIX 7 (5/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) As AM AM NM TY VM Cd AM AM NM TY VM Co AM AM NM TY VM Cr AM AM NM Cu AM.5 5 < AM NM TN VM 6.8 < Fe AM 5. < AM NM TN VM Hg AHg NHg T5Hg Mn AM AM NM TN VM Ni AM AM NM VM Pb AM AM NM TY VM Proftest SYKE MET 8/ 5

48 APPENDIX 7 (6/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) V AM AM NM TY VM Zn AM < AM NM < TY VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN VM As AM AM NM TN VM B mg/l AM mg/l AM mg/l NM mg/l TN mg/l VM Cd AM AM NM TN VM Co AM AM NM TN VM Cr AM AM NM TN VM Cu AM AM NM TN VM Proftest SYKE MET 8/

49 APPENDIX 7 (7/5) 5 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Fe AM AM NM TN VM Hg AHg NHg T5Hg Mn AM AM NM TN VM Mo AM AM NM TN VM Ni AM AM NM TN VM Pb AM AM NM TN VM Sb AM AM NM TN VM Se AM AM NM TN VM Sn AM NM V AM AM NM TN VM Proftest SYKE MET 8/ 7

50 APPENDIX 7 (8/5) 5 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Zn AM AM NM TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TY VM As AM AM NM TY VM B mg/l AM mg/l AM mg/l NM mg/l TY mg/l VM Cd AM AM NM TY VM Co AM AM NM TY VM Cr AM AM NM TY VM Cu AM AM NM TY VM Fe AM AM NM TY VM Proftest SYKE MET 8/

51 APPENDIX 7 (9/5) 6 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Hg AHg NHg T5Hg Mn AM AM NM TY VM Mo AM AM NM TY VM Ni AM AM NM TY VM Pb AM AM NM TY VM Sb AM AM NM TY VM Se AM AM NM TY VM Sn AM NM V AM AM NM TY VM Zn AM AM NM TY VM Proftest SYKE MET 8/ 9

52 APPENDIX 7 (/5) 7 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN As AM AM NM TN Cd AM AM NM TN Co AM AM NM TN Cr AM AM NM TN Cu AM AM NM TN Fe AM AM NM TN Hg AHg NHg T5Hg Mn AM AM NM TN Mo AM AM NM TN Ni AM AM NM TN Pb AM AM NM TN Proftest SYKE MET 8/

53 APPENDIX 7 (/5) 7 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Sb AM AM NM.78 < TN5.69 < Se AM AM NM TN V AM AM NM TN Zn AM AM NM TN Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN TY VM As AM AM NM TN TY VM B mg/l AM mg/l AM mg/l NM mg/l TN mg/l TY mg/l VM Cd AM AM NM TN TY VM Proftest SYKE MET 8/ 5

54 APPENDIX 7 (/5) 8 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Co AM AM NM TN TY VM Cr AM AM NM TN TY VM Cu AM AM NM TN TY VM Fe AM AM NM TN TY VM Hg AHg NHg T5Hg Mn AM AM NM TN TY VM Mo AM AM NM TN TY VM Ni AM AM NM TN TY VM Proftest SYKE MET 8/

55 APPENDIX 7 (/5) 8 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Pb AM AM NM TN TY VM Sb AM AM NM TN TY VM Se AM AM NM TN TY VM V AM AM NM TN TY VM Zn AM AM NM TN TY VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM As AM AM NM. 5 < Cd AM AM NM Cr AM.5 5 < AM NM Cu AM.5 5 < AM 75.5 < NM Proftest SYKE MET 8/ 5

56 APPENDIX 7 (/5) 9 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Fe AM 5. < AM NM Hg AHg NHg.89 5 < Mn AM AM NM Ni AM AM NM Pb AM AM NM Zn AM < AM NM < Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM TN As AM TN Cd AM TN Co AM TN Cr AM TN Cu AM TN Fe AM TN Hg AHg T5Hg Mn AM TN Mo AM TN Ni AM TN Proftest SYKE MET 8/

57 APPENDIX 7 (5/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Pb AM TN Sb AM TN Se AM TN Zn AM TN Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM B mg/l AM mg/l AM mg/l NM Cd AM. < AM NM. < Cr AM AM NM Cu AM AM NM Fe AM AM NM Mn AM AM NM Ni AM AM NM Pb AM AM NM.6 5 < Zn AM AM NM Proftest SYKE MET 8/ 55

58 APPENDIX 7 (6/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM NM TN VM As AM NM. 5 < TN VM 6.8 < B mg/l AM mg/l NM 5.8 < mg/l TN mg/l VM Cd AM NM. <5.... TN VM.68 5 < Cr AM NM TN VM Cu AM NM TN VM 6.8 < Fe AM NM TN VM Mn AM NM TN VM Mo AM NM 8.96 < TN VM Ni AM NM TN VM Pb AM NM.6 5 < TN VM < Sb AM NM.78 < TN VM < Proftest SYKE MET 8/

59 APPENDIX 7 (7/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Se AM NM.8 < TN VM 6.6 < Sn AM NM V AM NM.9 5 < TN VM Zn AM NM < TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM TY As AM AM TY Cd AM AM TY Co AM AM TY Cr AM AM TY Cu AM AM TY Fe AM AM TY Mn AM AM TY Ni AM AM TY Pb AM TY Proftest SYKE MET 8/ 57

60 APPENDIX 7 (8/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Zn AM AM TY Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN TY VM As AM AM NM TN TY VM Cd AM AM NM TN TY VM Co AM AM NM TN TY VM Cr AM AM NM TN TY VM Cu AM AM NM TN TY VM Fe AM AM NM TN TY VM Proftest SYKE MET 8/

61 APPENDIX 7 (9/5) 5 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Hg AHg NHg T5Hg Mn AM AM NM TN TY VM Mo AM AM NM TN TY VM Ni AM AM NM TN TY VM Pb AM AM NM TN TY VM Sb AM AM NM TN TY VM Se AM AM NM TN TY VM Sn AM NM.5 5 < V AM < AM NM TN TY VM Proftest SYKE MET 8/ 59

62 APPENDIX 7 (/5) 5 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Zn AM AM NM TN TY VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM NM VM As AM NM VM B mg/l AM mg/l NM mg/l VM Cd AM NM VM Co AM NM VM Cr AM NM VM Cu AM NM VM Fe AM NM VM Mn AM NM VM Mo AM NM VM Ni AM NM VM Pb AM NM VM Sb AM NM VM Proftest SYKE MET 8/

63 APPENDIX 7 (/5) 6 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Se AM NM VM Sn AM V AM NM VM Zn AM NM VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cd AM. < AM < NM. <.... Cu AM AM NM Fe AM AM NM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TY VM As AM AM NM TY VM B mg/l AM mg/l AM mg/l NM mg/l TY mg/l VM Cd AM AM NM TY VM Proftest SYKE MET 8/ 6

64 APPENDIX 7 (/5) 8 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Co AM AM NM TY VM Cr AM AM NM TY VM Cu AM AM NM TY VM Fe AM AM NM TY VM Mn AM AM NM TY VM Mo AM AM NM TY VM Ni AM AM NM TY VM Pb AM AM NM TY VM V AM AM NM TY VM Proftest SYKE MET 8/

65 APPENDIX 7 (/5) 8 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Zn AM AM NM TY VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TY VM As AM AM NM TY VM B mg/l AM mg/l AM mg/l NM mg/l TY mg/l VM Cd AM AM NM TY VM Co AM AM NM TY VM Cr AM AM NM TY VM Cu AM AM NM TY VM Fe AM AM NM TY VM Proftest SYKE MET 8/ 6

66 APPENDIX 7 (/5) 9 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Hg AHg NHg T5Hg Mn AM AM NM TY VM Mo AM AM NM TY VM Ni AM AM NM TY VM Pb AM AM NM TY VM Sb AM AM NM TY VM Se AM AM NM TY VM Sn AM NM V AM AM NM TY VM Zn AM AM NM TY VM Proftest SYKE MET 8/

67 APPENDIX 7 (5/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM As AM AM NM Cd AM AM NM Cr AM AM NM Cu AM AM NM Fe AM AM NM Mn AM AM NM Ni AM AM NM Pb AM AM NM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN TY VM As AM AM NM TN TY VM B mg/l AM.5 < mg/l AM mg/l NM 5.8 < mg/l TN mg/l TY mg/l VM Proftest SYKE MET 8/ 65

68 APPENDIX 7 (6/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cd AM AM NM TN TY VM Co AM AM NM TN TY VM Cr AM AM NM TN TY VM Cu AM AM NM TN TY VM Fe AM AM NM TN TY VM Hg AHg NHg T5Hg Mn AM AM NM TN TY VM Mo AM AM NM TN TY VM Proftest SYKE MET 8/

69 APPENDIX 7 (7/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Ni AM AM NM TN TY VM Pb AM AM NM TN TY VM Sb AM AM NM TN TY VM Se AM AM NM TN TY VM V AM AM NM TN TY VM Zn AM AM NM TN TY VM Proftest SYKE MET 8/ 67

70 APPENDIX 7 (8/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TN VM As AM AM NM TN VM B mg/l AM mg/l AM mg/l NM mg/l TN mg/l VM Cd AM AM NM TN VM Co AM AM NM TN VM Cr AM AM NM TN VM Cu AM AM NM TN VM Fe AM AM NM TN VM Hg AHg NHg T5Hg Mn AM AM NM TN VM Proftest SYKE MET 8/

71 APPENDIX 7 (9/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Mo AM AM NM TN VM Ni AM AM NM TN VM Pb AM AM NM TN VM Sb AM AM NM TN VM Se AM AM NM TN VM Sn AM NM V AM AM NM TN VM Zn AM AM NM TN VM Proftest SYKE MET 8/ 69

72 APPENDIX 7 (/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) As AM AM NM TN VM Cd AM AM NM TN VM Cu AM AM NM TN VM Hg AHg NHg T5Hg Ni AM AM NM TN VM Pb AM AM NM TN VM Zn AM AM NM TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cd AM < NM. <.... TN TY VM Cr AM NM TN TY VM Proftest SYKE MET 8/

73 APPENDIX 7 (/5) Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cu AM NM TN TY VM Fe AM NM TN TY VM Pb AM NM.6 5 < TN TY VM < Zn AM NM TN TY VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM TN Co AM TY Cr AM TY Fe AM TY Zn AM TY Proftest SYKE MET 8/ 7

74 APPENDIX 7 (/5) 6 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Al AM AM NM TY VM As AM AM NM TY VM B mg/l AM mg/l AM mg/l NM mg/l TY mg/l VM Cd AM AM NM TY VM Co AM AM NM TY VM Cr AM AM NM TY VM Cu AM AM NM TY VM Fe AM AM NM TY VM Hg AHg NHg T5Hg Mn AM AM NM TY VM Proftest SYKE MET 8/

75 APPENDIX 7 (/5) 6 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Mo AM AM NM TY VM Ni AM AM NM TY VM Pb AM AM NM TY VM Sb AM AM NM TY VM Se AM AM NM TY VM Sn AM NM V AM AM NM TY VM Zn AM AM NM TY VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) As AM 5 5 <. 6. NM. 5 < VM 6.8 < Cd AM < NM. <.... VM.68 5 < Proftest SYKE MET 8/ 7

76 APPENDIX 7 (/5) 7 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Co AM NM. 5 < VM.5 5 < Cr AM NM < VM.5 5 < Cu AM 75.5 < NM < VM 6.8 < Fe AM NM VM Mn AM NM VM Ni AM NM VM Pb AM 9. < NM.6 5 < VM Se AM 75 < NM.8 < VM 6.6 < Zn AM NM VM.5 5 < Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cd AM AM NM TN VM Co AM AM NM TN VM Cr AM AM NM TN VM Proftest SYKE MET 8/

77 APPENDIX 7 (5/5) 8 Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Cu AM AM NM TN VM Fe AM AM NM TN VM Pb AM AM NM TN VM Zn AM AM NM TN VM Analyte Unit Sample Assigned value *sp, % Lab's result Md Mean SD SD% n (stat) Hg AHg NHg T5Hg Pb AM AM NM TN VM Proftest SYKE MET 8/ 75

78 APPENDIX 8 (/5) APPENDIX 8: Summary of the s Analyte Sample % Al AM. S S. S S u S S. u S.. S S u S S q. S. 76. AM. q S. S S S q S.. S.. S S S S S q S S q 76.9 NM. S S. S S. S... S.. S S S S S q. S S 86. TN5.. S. S S S S Q. Q S.. S. Q 7. TY5. S S... S.. S. S VM. S S. S S q S S..... S S. S.... S 8. As AM.. S. S S S U S... S S S S S S U AM S S S S S S S S S.... S S S U S u. S. S 88.5 NM.. S. S S. S S.... S S S U S TN5 S. S S S S S S S. U S.. S. S 9.8 TY5. S Q.... S. S. S VM.. S. S S S S S.... S S S. S B AM.. S. S S u S S S. S... S. 7. AM. S S. S S q S S S. S... S u 87.5 NM.. S. S S. S S S. S... S. 8.6 TN5.. S. S S q S S.. S.... u 7. TY VM. S S. S S S S S S. S.... u 9.8 Cd AM.. S. S S u u S.. S. S S S S S S AM S S S. S S S S S.. S. S S S S S U. S S S 9.9 NM.. S. S S. S S.. S. S S S S S U TN5 S. S. S S S S S. S S.. S. S 88. TY5. S S... S S. S. S VM. S S. S S S S S.... S S S. S Co AM. S S. S S S q.... q S S S S S AM S S S. S S S S..... S S S S S.. S NM. S S. S S. q..... S S S S S TN5 S. S u S S S S S. S S.. S TY5. S S S. S. S..... VM. S S. S S S u..... S S S. S Cr AM.. S. S S S S q... S q S S S S... S. 8.6 AM. S S q S S S S Q.... S S S S S U. S S S 69. NM.. S. S S. S..... u S S S S S.. S S 86. TN5.. S S S S S S S. S S.. S. S 87.5 TY5. S S... S.. S. S VM. S S. S S S S S..... S S. S.... S 9. Cu AM U. S. S S q S.. U S S. S S S S... S. 7. AM S S S. S S S q... S. S S S S S.. S S S 85.7 NM S S S. S S. q S.. S. S S S S S S.. S U 78.6 TN5 S. S. S S S S..... S S. S S.. S. U 8. TY5. S S.. S. S VM.. S. S S S S S S. S Proftest SYKE MET 8/

79 APPENDIX 8 (/5) Analyte Sample % Fe AM. S S Q S S S q... S.. S S q S... S. 7.8 AM. S S S S S S S... S. S S S S S S. S S Q 86.7 NM. S S. S S. S... S. S S S S S S.. S S 8.6 TN5.. S S S S S S..... q Q. S S.. S. S 76.5 TY5. S u.. S. S VM. S S. S S S S..... S S S. S.... S 9.5 Hg AHg. S S. S S.. q... q S S S S S S. S NHg.. S.. S S S S S S T5Hg. S S. S S.. S... q S u S S S.. S Mn AM. S S q S S S S... S. S S S S S S.. S AM. S S S S S S S... S. S S S S S S. S S S 96. NM. S S. S S. S... S. S S S S S S.. S S 9. TN5.. S S S S q S..... S U. S S.. S. S 86.7 TY5. S q.. S. S VM. S S. S S S S..... S S S. S.... S 9.7 Mo AM. S S. S S S S... S.. S S U S AM. S S q S S S S... S.. S q S S.. S. S 9. NM.. S. S S. S... S.. S S S S TN5.. S S S S q S S. S S.. S. q 85.7 TY5. S u.. S. S VM. U S. S S S S Q S. S.... S 8. Ni AM S. S. S S S S S... S S S S S S S.. S. 96. AM S S S S S S S S S.... S S S S S U. S S S 85.7 NM. S S. S S. q S.... q S S S S S.. S S 87.5 TN5 U. S S S S S S. S.... S. S S.. S. S 9. TY5. S S... S.. S. S..... VM.. S. S S S S S.... S S S. S.... U 9. Pb AM.. S. S S q U S.. S S S S S S S u.. Q. 7. AM. S S S S S S S S.. S. S S S U S U. S S S 8. NM.. S. S S. u q.. S. S S S S S S TN5.. S u S S q S S. U S.. S. S 7. TY5. S S... S S. S. S VM.. S. S S u S S.... S S S. S Sb AM.. S. S S U U S S S S AM. q S S S S S u S S S S.. S. S 8. NM.. S. S S. U S S. S TN5.. S S S S S S S. S S.. S. S TY5. S S. S VM.. S. S S S S S S. S..... Se AM.. S. S S q S S S S S AM. Q S q S S S S S S q S.. S. S 8. NM.. S. S S. S S S S S..... TN5.. S S S S S S Q. S S.. S. S 9.9 TY5. U S. S VM.. S. S S S S S S. S..... Sn AM. U S. S S S S S q 8.6 NM.. S. S S S S q 77.8 Proftest SYKE MET 8/ 77

80 APPENDIX 8 (/5) Analyte Sample % V AM.. S. S S S S.... S S S S u S AM. S S. S S S S..... S S S S S.... S 9. NM.. S. S S. S..... S S S S S..... TN5.. S. S S S S Q. S S.... S 9.7 TY5. q S S. S. S VM.. S. S S S Q..... S S S. S.... S 9. Zn AM S S S. S S q S... S S. S S S S... S AM S S S S S S S S... S. Q S S S S S. S S Q 8. NM S S S. S S. S q.. S.. S S S S... S. 7.8 TN5 S. S S S S S S S. S S.. S. S 88.9 TY5. S S S. S. S..... VM. S S. S S S S..... S S S. S.... S 9.5 % accredited Analyte Sample % Al AM S S Q. S S q S S... S AM S S.. S S S S S.. U Q NM. S U. S S S S S... U TN5. S..... S S.. U TY5 S S.. S S. S.... Q VM. S u. S S. S S... Q As AM S S S. S S S S S q.. S AM S S.. S S S S S S.. q NM. S S. S S S S S S.. S TN5. S..... S S S TY5 S S.. U S. S.... S VM. S S. S S. S S S.. Q B AM.. S. u S.. u... U AM.... S S. S S... S NM.. S. u S.. u... S TN S Q TY VM.. S. S S. S S... S Cd AM u S S. u S q S S S.. S. U AM S S.. S S S S S S.. S. U NM. Q S. q S q S S S.. S. U TN5. S..... S S S U... u TY5 S S.. S S. S.. U. S VM. S S. S S. S S S Q. S. U Co AM S S S. S S. S S... S. q AM S S.. S S. S S.. u S u u NM. S S. S S. S S... S. u TN5. S..... S S..... u TY5 S S.. S S. S... S S VM. S S. S S. S S... S. u Proftest SYKE MET 8/

81 APPENDIX 8 (/5) Analyte Sample % Cr AM q S S. S S S S S... S. U AM S S.. S S S S q. u u Q u u NM. S S. S S S S S. U. S. U TN5. S..... S S. Q... u TY5 S S.. S S. S.. U u S VM. S S. S S. S S. U. S. u Cu AM U S S U S S S S S u.. S. U AM S S. u S S u S S S u. S. S NM. S S U S S u S S S S. Q. U TN5. S..... S S S U... U TY5 S S.. S S. S.. U. S VM. S u. S S. S S u U. S. U Fe AM S S U U S S S S q... S. U AM S S. S S S S S S. u S S u U NM. S U Q S S S S S. S. S u u TN5. S..... S Q. S... U TY5 S S.. S S. S.. S q S VM. S S. S S. S S. S. S u u Hg AHg. S... S. S S S.. u.. S NHg. Q... S. S S S.. U.. S T5Hg. S... S. S S S.. S.. S Mn AM S S u. S S S S q... S AM S S.. S S S S S... S u NM. S S. S S S S q... S u TN5. S..... S S TY5 S S.. S S. S.... S VM. S S. S S. S S... S u Mo AM. S S. S S. S q... u AM. S.. S S. S S... S NM. S S. S S. S S... u TN5. S..... S S TY5. U.. S S. S.... S VM. S S. q S. S S... S Ni AM u S S. S S S S S S.. S AM S S.. S S S S q S.. Q u NM. S S. S S S S S S.. S u TN5. S..... S S S TY5 S S.. S S. S.... S VM. S S. S S. S S S.. S u Pb AM. S S. S S u S S S.. q. U S AM S S.. S S q S S S u. Q. Q S NM. S Q. S S S S S q.. q. U S TN5. S..... S S S U... u S TY5 S S.. S S. S.. U. S VM. S S. S q. S S S.. S u u S Proftest SYKE MET 8/ 79

82 APPENDIX 8 (5/5) Analyte Sample % Sb AM. S S.. S. S q... u AM. S... S. S S... q NM. S S.. S. S S... S TN5. S..... S S TY5. S... S. S.... Q VM. S S.. S. S S... S Se AM. S S.. S. S S... S AM. S... S. S S... S NM. S S.. S. S S... S TN5. S..... S S TY5. S... S. S.... S VM. S S.. S. S S... S Sn AM. S S.. S.. S... S NM..... S.. U... S V AM. S S. S S. S S... S AM. S.. S S. S q... S NM. S S. S S. S S... S TN5. S..... S S TY5. S.. q S. S.... S VM. S S. S S. S S... S Zn AM u S S. S S. S S S.. S. U AM S S.. S S. S S S u S S u u NM. S U. S S. S S U U. Q u U TN5. q..... S S S S... U TY5 S S.. S S. S.. S S S VM. S S. S S. S S S U. S. U % accredited S satisfactory ( < z < ), Q questionable ( < z < ), q questionable ( < z < ), U unsatisfactory (z > ), and u unsatisfactory (z < ), respectively. bold accredited, italics nonaccredited, normal other % percentage of satisfactory results Satisfactory results in total, % in all: 86 % in accredited: 9 % in nonaccredited: 76 8 Proftest SYKE MET 8/

83 APPENDIX 9 (/) APPENDIX 9: s in ascending order Analyte Al Sample AM ê Analyte Al Sample AM Analyte Al Sample NM Proftest SYKE MET 8/ 8

84 APPENDIX 9 (/) Analyte Al Sample TN Analyte Al Sample TY Analyte Al Sample VM ê Proftest SYKE MET 8/

85 APPENDIX 9 (/) Analyte As Sample AM Analyte As Sample AM ê Analyte As Sample NM Proftest SYKE MET 8/ 8

86 APPENDIX 9 (/) Analyte As Sample TN Analyte As Sample TY Analyte As Sample VM Proftest SYKE MET 8/

87 APPENDIX 9 (5/) Analyte B Sample AM ê ê Analyte B Sample AM ê Analyte B Sample NM ê ê Proftest SYKE MET 8/ 85

88 APPENDIX 9 (6/) Analyte B Sample TN Analyte B Sample VM ê Analyte Cd Sample AM ê ê ê Proftest SYKE MET 8/

89 APPENDIX 9 (7/) Analyte Cd Sample AM Analyte Cd Sample NM Analyte Cd Sample TN5 ê Proftest SYKE MET 8/ 87

90 APPENDIX 9 (8/) Analyte Cd Sample TY Analyte Cd Sample VM Analyte Co Sample AM Proftest SYKE MET 8/

91 APPENDIX 9 (9/) Analyte Co Sample AM ê ê Analyte Co Sample NM ê Analyte Co Sample TN5 ê ê Proftest SYKE MET 8/ 89

92 APPENDIX 9 (/) Analyte Co Sample TY Analyte Co Sample VM ê Analyte Cr Sample AM Proftest SYKE MET 8/

93 APPENDIX 9 (/) Analyte Cr Sample AM ê ê ê ê Analyte Cr Sample NM Analyte Cr Sample TN5 ê Proftest SYKE MET 8/ 9

94 APPENDIX 9 (/) Analyte Cr Sample TY Analyte Cr Sample VM ê Analyte Cu Sample AM ê Proftest SYKE MET 8/

95 APPENDIX 9 (/) Analyte Cu Sample AM ê ê ê Analyte Cu Sample NM ê Analyte Cu Sample TN Proftest SYKE MET 8/ 9

96 APPENDIX 9 (/) Analyte Cu Sample TY Analyte Cu Sample VM ê ê Analyte Fe Sample AM Proftest SYKE MET 8/

97 APPENDIX 9 (5/) Analyte Fe Sample AM ê 7 ê Analyte Fe Sample NM ê Analyte Fe Sample TN Proftest SYKE MET 8/ 95

98 APPENDIX 9 (6/) Analyte Fe Sample TY Analyte Fe Sample VM ê ê Analyte Hg Sample AHg ê Proftest SYKE MET 8/

99 APPENDIX 9 (7/) Analyte Hg Sample NHg Analyte Hg Sample T5Hg Analyte Mn Sample AM ê Proftest SYKE MET 8/ 97

100 APPENDIX 9 (8/) Analyte Mn Sample AM ê Analyte Mn Sample NM ê Analyte Mn Sample TN Proftest SYKE MET 8/

101 APPENDIX 9 (9/) Analyte Mn Sample TY Analyte Mn Sample VM ê Analyte Mo Sample AM ê Proftest SYKE MET 8/ 99

102 APPENDIX 9 (/) Analyte Mo Sample AM Analyte Mo Sample NM Analyte Mo Sample TN Proftest SYKE MET 8/

103 APPENDIX 9 (/) Analyte Mo Sample TY Analyte Mo Sample VM Analyte Ni Sample AM ê Proftest SYKE MET 8/

104 APPENDIX 9 (/) Analyte Ni Sample AM ê Analyte Ni Sample NM ê Analyte Ni Sample TN Proftest SYKE MET 8/

105 APPENDIX 9 (/) Analyte Ni Sample TY Analyte Ni Sample VM ê Analyte Pb Sample AM ê ê Proftest SYKE MET 8/

106 APPENDIX 9 (/) Analyte Pb Sample AM ê Analyte Pb Sample NM ê Analyte Pb Sample TN5 ê Proftest SYKE MET 8/

107 APPENDIX 9 (5/) Analyte Pb Sample TY Analyte Pb Sample VM ê ê Analyte Sb Sample AM Proftest SYKE MET 8/ 5

108 APPENDIX 9 (6/) Analyte Sb Sample AM ê Analyte Sb Sample NM Analyte Sb Sample TN Proftest SYKE MET 8/

109 APPENDIX 9 (7/) Analyte Sb Sample TY Analyte Sb Sample VM Analyte Se Sample AM Proftest SYKE MET 8/ 7

110 APPENDIX 9 (8/) Analyte Se Sample AM Analyte Se Sample NM Analyte Se Sample TN Proftest SYKE MET 8/

111 APPENDIX 9 (9/) Analyte Se Sample TY Analyte Se Sample VM Analyte Sn Sample AM Proftest SYKE MET 8/ 9

112 APPENDIX 9 (/) Analyte Sn Sample NM Analyte V Sample AM ê Analyte V Sample AM Proftest SYKE MET 8/

113 APPENDIX 9 (/) Analyte V Sample NM Analyte V Sample TN Analyte V Sample TY Proftest SYKE MET 8/

114 APPENDIX 9 (/) Analyte V Sample VM Analyte Zn Sample AM ê Analyte Zn Sample AM ê ê ê Proftest SYKE MET 8/

115 APPENDIX 9 (/) Analyte Zn Sample NM ê Analyte Zn Sample TN Analyte Zn Sample TY Proftest SYKE MET 8/

116 APPENDIX 9 (/) Analyte Zn Sample VM Proftest SYKE MET 8/

117 APPENDIX (/) APPENDIX : Results grouped according to the methods In figures: The dashed lines describe the standard deviation for the proficiency assessment, the red solid line shows the assigned value, the shaded area describes the expanded measurement uncertainty of the assigned value, and the arrow describes the value outside the scale. Analyte Al Sample AM ê GAAS ICPOES ICPMS Other method Analyte Al Sample AM GAAS ICPOES ICPMS Other method Proftest SYKE MET 8/ 5

118 APPENDIX (/) Analyte Al Sample NM ICPOES ICPMS Hydride generation AAS tech nique Other method Analyte Al Sample TN ICPOES ICPMS Other method Analyte Al Sample TY FAAS GAAS ICPOES ICPMS 6 Proftest SYKE MET 8/

119 APPENDIX (/) Analyte Al Sample VM ê GAAS ICPOES ICPMS Analyte As Sample AM 5,,8,,,6,,8 5 5 GAAS ICPOES ICPMS Hydride generation AAS technique Analyte As 5 Sample AM 5 5 ê GAAS ICPOES ICPMS Hydride generation AAS technique Hydride generation ICPOES technique Proftest SYKE MET 8/ 7

120 APPENDIX (/) Analyte As Sample NM,,8,6,,,,8,6,, 5 5 GAAS ICPOES ICPMS Hydride generation AAS technique Analyte As Sample TN GAAS ICPOES ICPMS Hydride generation AAS technique Hydride generation ICPOES technique Analyte As Sample TY GAAS ICPOES ICPMS Hydride generation AAS technique 8 Proftest SYKE MET 8/

121 APPENDIX (5/) Analyte As Sample VM 8,9 8, 7, 6,5 5,7,9, 5 5 GAAS ICPOES ICPMS Hydride generation AAS technique Analyte B Sample AM mg/l ê ê 5 5 ICPOES ICPMS Analyte B Sample AM mg/l 9 8 ê ICPOES ICPMS Proftest SYKE MET 8/ 9

122 APPENDIX (6/) Analyte B Sample NM 9 7 mg/l 5 9 ê ê 5 ICPOES ICPMS Analyte B Sample TN5 9 mg/l ICPOES ICPMS Analyte B Sample TY5 7 5 mg/l ICPOES ICPMS Proftest SYKE MET 8/

123 APPENDIX (7/) Analyte B Sample VM mg/l 5 ê ICPOES ICPMS Analyte Cd,55 Sample AM,5,5,,5,,5, ê ê FAAS GAAS ICPOES ICPMS Analyte Cd 8, 7,8 7, 7, Sample AM 6,6 6, 5,8 5, 5,, FAAS GAAS ICPOES ICPMS Proftest SYKE MET 8/

124 APPENDIX (8/) Analyte Cd,5 Sample NM,,5,,5, 5 5 FAAS GAAS ICPOES ICPMS Analyte Cd Sample TN ê 5 5 FAAS GAAS ICPOES ICPMS Analyte Cd Sample TY FAAS GAAS ICPOES ICPMS Proftest SYKE MET 8/

125 APPENDIX (9/) Analyte Cd,6 Sample VM,,,,8,6,,,,8,6 5 5 FAAS GAAS ICPOES ICPMS Analyte Co Sample AM,5,,,9,7,5,,,9,7,5 5 5 FAAS GAAS ICPOES ICPMS Analyte Co Sample AM ê ê 5 5 FAAS GAAS ICPOES ICPMS Proftest SYKE MET 8/

126 APPENDIX (/) Analyte Co Sample NM,9,7,5,,,9,7,5, ê, 5 5 FAAS GAAS ICPOES ICPMS Analyte Co Sample TN ê ê 5 5 FAAS GAAS ICPOES ICPMS Analyte Co Sample TY FAAS GAAS ICPOES ICPMS Proftest SYKE MET 8/

127 APPENDIX (/) Analyte Co Sample VM,,,,8,6,,,,8,6 ê, 5 5 FAAS GAAS ICPOES ICPMS Analyte Cr,5 Sample AM,,,9,7,5,,,9,7,5 5 5 FAAS GAAS ICPOES ICPMS Analyte Cr Sample AM ê ê ê ê FAAS GAAS ICPOES ICPMS Proftest SYKE MET 8/ 5

128 APPENDIX (/) Analyte Cr Sample NM 9, 8,6 8, 7,8 7, 7, 6,6 6, 5,8 5, 5, 5 5 FAAS GAAS ICPOES ICPMS Analyte Cr Sample TN ê 5 5 FAAS GAAS ICPOES ICPMS Analyte Cr Sample TY FAAS GAAS ICPOES ICPMS 6 Proftest SYKE MET 8/

129 APPENDIX (/) Analyte Cr 8 Sample VM ê 5 5 FAAS GAAS ICPOES ICPMS Analyte Cu 5,6 Sample AM 5,,8,,,6 ê, FAAS GAAS ICPOES ICPMS Other method Analyte Cu Sample AM ê ê ê FAAS GAAS ICPOES ICPMS Other method Proftest SYKE MET 8/ 7

130 APPENDIX (/) Analyte Cu Sample NM 9 ê FAAS GAAS ICPOES ICPMS Other method Analyte Cu Sample TN FAAS GAAS ICPOES ICPMS Analyte Cu Sample TY FAAS ICPOES ICPMS 8 Proftest SYKE MET 8/

131 APPENDIX (5/) Analyte Cu 8,6 Sample VM 7,8 7, 6, 5,,6,8 ê ê 5 5 FAAS ICPOES ICPMS Analyte Fe Sample AM FAAS ICPOES ICPMS Other method Analyte Fe Sample AM ê ê FAAS ICPOES ICPMS Other method Proftest SYKE MET 8/ 9

132 APPENDIX (6/) Analyte Fe Sample NM ê FAAS ICPOES ICPMS Other method Analyte Fe Sample TN FAAS ICPOES ICPMS Analyte Fe Sample TY FAAS ICPOES ICPMS Proftest SYKE MET 8/

133 APPENDIX (7/) Analyte Fe Sample VM ê ê 5 5 FAAS ICPOES ICPMS Analyte Hg Sample AHg,7,67,6,59,55,5,7,,9,5, 5 5 ê CVAAS CVAFS CVICPMS technique ICPMS Hydride generation AAS technique IDICPMS Other method Analyte Hg Sample NHg,,,,,9,8,7,6,5, 5 5 CVAAS CVAFS CVICPMS technique ICPMS IDICPMS Proftest SYKE MET 8/

134 APPENDIX (8/) Analyte Hg Sample T5Hg,6,,,,8,6,,,,8,6 5 5 CVAAS CVAFS CVICPMS technique ICPMS IDICPMS Other method Analyte Mn Sample AM 8 6 ê FAAS GAAS ICPOES ICPMS Analyte Mn Sample AM ê FAAS GAAS ICPOES ICPMS Proftest SYKE MET 8/

135 APPENDIX (9/) Analyte Mn Sample NM ê FAAS GAAS ICPOES ICPMS Analyte Mn Sample TN FAAS ICPOES ICPMS Analyte Mn Sample TY FAAS ICPOES ICPMS Proftest SYKE MET 8/

136 APPENDIX (/) Analyte Mn Sample VM ê FAAS ICPOES ICPMS Analyte Mo Sample AM ê 5 5 ICPOES ICPMS Analyte Mo Sample AM 5 5 ICPOES ICPMS Proftest SYKE MET 8/

137 APPENDIX (/) Analyte Mo Sample NM,8,, 9, 8,6 7,8 7, 6, 5, 5 5 ICPOES ICPMS Analyte Mo Sample TN ICPOES ICPMS Analyte Mo Sample TY FAAS ICPOES ICPMS Proftest SYKE MET 8/ 5

138 APPENDIX (/) Analyte Mo Sample VM ICPOES ICPMS Analyte Ni Sample AM,8, 9, 8, 7,6 6,8 ê 6, GAAS ICPOES ICPMS Analyte Ni Sample AM ê FAAS GAAS ICPOES ICPMS 6 Proftest SYKE MET 8/

139 APPENDIX (/) Analyte Ni Sample NM 9 8 ê FAAS GAAS ICPOES ICPMS Analyte Ni Sample TN GAAS ICPOES ICPMS Hydride generation AAS technique Analyte Ni Sample TY FAAS GAAS ICPOES ICPMS Proftest SYKE MET 8/ 7

140 APPENDIX (/) Analyte Ni Sample VM 8,8 8, 7, 6, 5,6,8 ê, 5 5 FAAS GAAS ICPOES ICPMS Analyte Pb Sample AM 5,7 5,,9,5,,7, ê ê FAAS GAAS ICPOES ICPMS IDICPMS Analyte Pb Sample AM ê FAAS GAAS ICPOES ICPMS IDICPMS 8 Proftest SYKE MET 8/

141 APPENDIX (5/) Analyte Pb,5 Sample NM,,,9,7,5,,,9,7 ê,5 5 5 FAAS GAAS ICPOES ICPMS IDICPMS Analyte Pb 6 Sample TN ê FAAS GAAS ICPOES ICPMS IDICPMS Analyte Pb Sample TY FAAS GAAS ICPOES ICPMS Proftest SYKE MET 8/ 9

142 APPENDIX (6/) Analyte Pb Sample VM 8,9 8,5 8, 7,7 7, 6,9 6,5 6, 5,7 5,,9 ê ê 5 5 FAAS GAAS ICPOES ICPMS IDICPMS Analyte Sb Sample AM,,,8,6,,,,8 5 5 GAAS ICPOES ICPMS Analyte Sb Sample AM ê GAAS ICPOES ICPMS Hydride generation ICPOES tech nique Proftest SYKE MET 8/

143 APPENDIX (7/) Analyte Sb Sample NM,,9,8,7,6,5 5 ICPOES ICPMS Analyte Sb Sample TN GAAS ICPOES ICPMS Hydride generation ICPOES tech nique Analyte Sb Sample TY ICPOES ICPMS Proftest SYKE MET 8/

144 APPENDIX (8/) Analyte Sb Sample VM 7, 6,7 6, 5,9 5,5 5,,7,,9 5 5 ICPOES ICPMS Analyte Se Sample AM 5,6 5,,8,,,6, 5 5 GAAS ICPOES ICPMS Analyte Se Sample AM GAAS ICPOES ICPMS Hydride generation ICPOES tech nique Proftest SYKE MET 8/

145 APPENDIX (9/) Analyte Se Sample NM,,9,5,,7,,9 5 5 GAAS ICPOES ICPMS Analyte Se Sample TN5 5, 8, 5,,8 8,6 5,, 9, 5,8,6 5 5 GAAS ICPOES ICPMS Hydride generation ICPOES tech nique Analyte Se Sample TY ICPOES ICPMS Proftest SYKE MET 8/

146 APPENDIX (/) Analyte Se Sample VM 8,8 8, 7, 6, 5,6,8, 5 5 ICPOES ICPMS Analyte Sn Sample AM ICPOES ICPMS Analyte Sn Sample NM 5,,6,,8,,,6,,8 5 ICPOES ICPMS Proftest SYKE MET 8/

147 APPENDIX (/) Analyte V Sample AM 9,7 9, 8,9 8,5 8, 7,7 7, 6,9 6,5 6, 5,7 ê 5, 5 5 GAAS ICPOES ICPMS Analyte V Sample AM GAAS ICPOES ICPMS Analyte V Sample NM 5,5 5,,7,,9,5, 5 5 GAAS ICPOES ICPMS Proftest SYKE MET 8/ 5

148 APPENDIX (/) Analyte V Sample TN GAAS ICPOES ICPMS Analyte V Sample TY FAAS GAAS ICPOES ICPMS Analyte V Sample VM GAAS ICPOES ICPMS 6 Proftest SYKE MET 8/

149 APPENDIX (/) Analyte Zn,8 Sample AM, 9, 8, 7,6 6,8 ê 6, FAAS GAAS ICPOES ICPMS Analyte Zn Sample AM ê ê ê FAAS ICPOES ICPMS Analyte Zn 9,8 Sample NM 9, 9, 8,6 8, 7,8 7, 7, 6,6 6, 5,8 ê 5, FAAS ICPOES ICPMS Proftest SYKE MET 8/ 7

150 APPENDIX (/) Analyte Zn Sample TN FAAS ICPOES ICPMS Analyte Zn Sample TY FAAS ICPOES ICPMS Analyte Zn Sample VM FAAS ICPOES ICPMS 8 Proftest SYKE MET 8/

151 APPENDIX (/) APPENDIX : Significant differences in the results reported using different methods Boxplot figures: In the box the upper and lower limit included 5 % of the results. The dashed vertical line in the middle of the box is the median of the results. The vertical lines above and under the box describe the limits of 8 % of the results. The black dots describe the highest and smallest results within the center 9 % of the results. Statistically significant differences between methods Method n Mean (mg/l) SD (mg/l) Method 6: ICPOES Method 6: ICPMS n= number of results; SD: standard deviation Method n Mean (mg/l) SD (mg/l) Method 6: ICPOES 6 5 Method 6: ICPMS n= number of results; SD: standard deviation Proftest SYKE MET 8/ 9

152 APPENDIX (/) Method n Mean (mg/l) SD (mg/l) Method 6: ICPOES Method 6: ICPMS n= number of results; SD: standard deviation 5 Proftest SYKE MET 8/

153 APPENDIX (/) APPENDIX : Estimation of the measurement uncertainties and examples of the reported values ESTIMATION PROCEDURE OF UNCERTAINTY: UC No: the procedure used for the estimation of the expanded measurement uncertainty at 95 % confidence level (k=).. Using the IQC data only from synthetic control sample and/or CRM (Xchart), see e.g. NORDTEST TR 57 ). Using MUkit measurement uncertainty software ).. Using the IQC data only from synthetic control sample and/or CRM (Xchart), see e.g. NORDTEST TR 57 ). Without MUkit measurement uncertainty software.. Using the IQC data from synthetic sample (Xchart) together with the IQC data from routine sample replicates (Rchart or r%chart), see e.g. NORDTEST TR 57 ). Using MUkit software.. Using the IQC data from synthetic sample (Xchart) together with the IQC data from routine sample replicates (Rchart or r%chart), see e.g. NORDTEST TR 57 ). Without MUkit software. 5. Using the IQC data and the results obtained in proficiency tests, see e.g. NORDTEST TR 57 ). Using MUkit software. 6. Using the IQC data and the results obtained in proficiency tests, see e.g. NORDTEST TR 57 ). Without MUkit software. 7. Using the data obtained in method validation. Using MUkit software. 8. Using the data obtained in method validation. Without MUkit software. 9. Using the "modeling approach" (GUM Guide or EURACHEM Guide Quantifying Uncertainty in Analytical Measurement) ). Other procedure, please specify. No uncertainty estimation IQC = internal quality control ) ) ) Proftest SYKE MET 8/ 5

154 APPENDIX (/) Analyte Al Sample AM 5 Uncertainty %, U% 5 5 Method Method Method Method 6 Method 8 Analyte Al Sample NM 5 Uncertainty %, U% Method Method Method Method 6 Method 8 Analyte Al Sample VM 5 Uncertainty %, U% Method Method Method Method 6 Method 8 5 Proftest SYKE MET 8/

155 APPENDIX (/) Analyte As Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte B Sample VM 5 Uncertainty %, U% Method Method Method Method 6 Method 8 Analyte Cd Sample AM Uncertainty %, U% 8 6 Method Method Method Method 6 Method 7 Method 8 Proftest SYKE MET 8/ 5

156 APPENDIX (/) Analyte Cd Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Co Sample AM Uncertainty %, U% 8 6 Method Method Method Method 6 Method 7 Method 8 Analyte Co Sample VM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 5 Proftest SYKE MET 8/

157 APPENDIX (5/) Analyte Cr Sample VM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Cu Sample AM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Cu Sample NM 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Proftest SYKE MET 8/ 55

158 APPENDIX (6/) Analyte Cu Sample TN5 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Fe Sample NM 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Fe Sample VM 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 56 Proftest SYKE MET 8/

159 APPENDIX (7/) Analyte Hg Sample AHg 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Method 9 Analyte Hg Sample NHg 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Method 9 Analyte Hg Sample T5Hg 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Method 9 Proftest SYKE MET 8/ 57

160 APPENDIX (8/) Analyte Mn Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Mo Sample AM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Mo Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 58 Proftest SYKE MET 8/

161 APPENDIX (9/) Analyte Mo Sample VM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Ni Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Ni Sample TN5 5 Uncertainty %, U% 5 5 Method Method Method Method 5 Method 6 Method 7 Method 8 Proftest SYKE MET 8/ 59

162 APPENDIX (/) Analyte Pb Sample AM 8 6 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Method 9 Analyte Pb Sample NM 8 6 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Method 9 Analyte Pb Sample TN5 5 Uncertainty %, U% 5 5 Method Method Method Method 5 Method 6 Method 7 Method 8 Method 9 6 Proftest SYKE MET 8/

163 APPENDIX (/) Analyte Sb Sample AM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Sb Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Sb Sample TN5 5 Uncertainty %, U% 5 5 Method Method Method Method 6 Method 7 Method 8 Proftest SYKE MET 8/ 6

164 APPENDIX (/) Analyte Se Sample AM 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Se Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Sn Sample AM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 8 6 Proftest SYKE MET 8/

165 APPENDIX (/) Analyte Sn Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 8 Analyte V Sample AM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte V Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Proftest SYKE MET 8/ 6

166 APPENDIX (/) Analyte Zn Sample NM 6 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 Analyte Zn Sample TN5 5 Uncertainty %, U% Method Method Method Method 5 Method 6 Method 7 Method 8 Analyte Zn Sample VM 5 Uncertainty %, U% Method Method Method Method 6 Method 7 Method 8 6 Proftest SYKE MET 8/

167 DOCUMENTATION PAGE Publisher Finnish Environment Institute Date March 5 Author(s) Mirja Leivuori, Riitta Koivikko, Timo SaraAho, Teemu Näykki, Katarina Björklöf, Keijo Tervonen, Sari Lanteri, Ritva Väisänen and Markku Ilmakunnas Title of publication Interlaboratory Proficiency Test 8/ Metals and mercury in waters Publication series and number Theme of publication Parts of publication/ other project publications Abstract Reports of the Finnish Environment Institute 7/5 The publication is available in the internet: helda.helsinki.fi/syke Proftest SYKE carried out the proficiency test (PT) for analysis of elements in waters in October. The measurements were: Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V, and Zn. The tested sample types were: artificial, natural water, municipal waste water and industrial waste water samples. In total 8 laboratories participated in the PT. In this proficiency test 86 % of the results were satisfactory when deviations of 5 % from the assigned values were accepted. Basically, the metrologically traceable concentration, calculated concentrations or the robust mean or mean of the results reported by the participant were used as the assigned values for measurements. The evaluation of the performance of the participants was carried out using. In some cases the evaluation of the performance was not possible e.g. due to the low number of the participants. Keywords water analysis, metals, Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V, Zn, water, environmental laboratories, proficiency test, interlaboratory comparisons Financier/ commissioner ISSN (pdf) ISBN (online) (pdf) No. of pages Language 67 English Restrictions Public Distributor Financier of publication Printing place and year Finnish Environment Institute (SYKE), neuvonta P.O. Box, FI5 Helsinki, Finland [email protected] Finnish Environment Institute (SYKE), P.O. Box, FI5 Helsinki, Finland Phone Helsinki 5 Proftest SYKE MET 8/ 65

168 KUVAILULEHTI Julkaisija Suomen ympäristökeskus Julkaisuaika Maaliskuu 5 Tekijä(t) Mirja Leivuori, Riitta Koivikko, Timo SaraAho, Teemu Näykki, Katarina Björklöf, Keijo Tervonen, Sari Lanteri, Ritva Väisänen and Markku Ilmakunnas Julkaisun nimi Laboratorioiden välinen pätevyyskoe 8/ Metallit ja elohopea vesistä Julkaisusarjan nimi ja numero Julkaisun teema Julkaisun osat/ muut saman projektin tuottamat julkaisut Tiivistelmä Suomen ympäristökeskuksen raportteja 7/5 Julkaisu on saatavana vain internetistä: helda.helsinki.fi/syke Proftest SYKE järjesti pätevyyskokeen ympäristönäytteitä analysoiville laboratorioille Lokakuusssa. Pätevyyskokeessa määritettiin synteettisestä näytteestä ja kolmesta erityyppisestä vesinäytteestä seuraavat metallit: Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V ja Zn. Pätevyyskokeeseen osallistui yhteensä 8 laboratoriota. Koko tulosaineistossa hyväksyttäviä tuloksia oli 86 %, kun vertailuarvosta sallittiin 5 %:n poikkeama. Laboratorioiden pätevyyden arviointi tehtiin zarvon avulla. Mittaussuureen vertailuarvona käytettiin metrologisesti jäljitettävää pitoisuutta, laskennallista pitoisuutta, osallistujien ilmoittamien tulosten robustia keskiarvoa tai keskiarvoa. Asiasanat Rahoittaja/ toimeksiantaja vesianalyysi, metallit, Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V, Zn, vesi ja ympäristölaboratoriot, pätevyyskoe, laboratorioiden välinen vertailumittaus ISSN (pdf) ISBN (verkkoj.) (pdf) Julkaisun jakelu Julkaisun kustantaja Sivuja Kieli 67 Englanti Luottamuksellisuus julkinen Painopaikka ja aika Helsinki 5 Suomen ympäristökeskus (SYKE), neuvonta PL, 5, Helsinki Sähköposti: [email protected] Suomen ympäristökeskus (SYKE), syke.fi PL, 5, Helsinki Puh Proftest SYKE MET 8/

169 PRESENTATIONSBLAD Utgivare Finlands miljöcentral Datum Mars 5 Författare Mirja Leivuori, Riitta Koivikko, Timo SaraAho, Teemu Näykki, Katarina Björklöf, Keijo Tervonen, Sari Lanteri, Ritva Väisänen and Markku Ilmakunnas Publikationens titel Provningsjämförelse 8/ Metaller i vatten och sediment Publikationsserie och nummer Publikationens tema Publikationens delar/ andra publikationer inom samma projekt Sammandrag Finlands miljöcentrals rapporter 7/5 Publikationen finns tillgänglig på internet: helda.helsinki.fi/syke Proftest SYKE genomförde en provningsjämförelse i oktober, som omfattade bestämningen av Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V och Zn i vatten. Tillsammans 8 laboratorier deltog i jämförelsen. I jämförelsen var 86 % av alla resultaten tillfredsställande, när total deviation på 5 % från referensvärdet accepterades. Som referensvärde av analytens koncentration användes mest det metrologiska spårbara värdet, teoretiska värdet robust medelvärdet eller medelvärdet av deltagarnas resultat. Resultaten värderades med hjälp av zvärden. Nyckelord vattenanalyser, metaller, Al, As, B, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V, Zn, provningsjämförelse, vatten och miljölaboratorier Finansiär/ uppdragsgivare ISSN (pdf) ISBN (online) (pdf) Sidantal Språk 67 Engelska Offentlighet Offentlig Distribution Förläggare Tryckeri/tryckningsort Finlands miljöcentral (SYKE), PB, 5 Helsingfors Epost: [email protected] Finlands miljöcentral (SYKE), PB, 5 Helsingfors Tel Epost: [email protected] Helsinki 5 Proftest SYKE MET 8/ 67

170 PROFICIENCY TEST SYKE 8/ ISBN (PDF) ISSN (online) SYKE FINNISH ENVIRONMENT INSTITUTE